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Potentials of Maximum Electron Resistance of Solid Electrolyte in the O2/Solid Electrolyte/Blocking Electrode Cell

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Abstract

Relations for calculating differential and overall electron resistances of the solid electrolyte (SE) in the cell O2/SE/blocking electrode, for temperature dependences of potentials of the maximum electron resistance, and for temperature coefficients of potentials of maximum resistance with the help of oxygen-penetrability constants are obtained. The relations are used to perform calculations for SE 0.85ZrO2+ 0.15CaO.

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoi 20, Yekaterinburg, 620219, Russia

    V. K. Gil'derman

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  1. V. K. Gil'derman
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Gil'derman, V.K. Potentials of Maximum Electron Resistance of Solid Electrolyte in the O2/Solid Electrolyte/Blocking Electrode Cell. Russian Journal of Electrochemistry 37, 1024–1028 (2001). https://doi.org/10.1023/A:1012358727433

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