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Crystal Structure of 1,10-Diazonia-18-crown-6 Bis(DL-glutamate)

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Abstract

The crystal structure of 1'10-diazonia-18-crown-6 bis(DL-glutamate) was studied by single crystalX-ray diffraction. The geometries of molecular ions, their packing in the crystal lattice were determined.The macrocyclic dication is located around the crystallographic inversion center i(000) and has an unusual, previously unknown conformation. The crystalline salt forms an infinite three-dimensional polymeric network linked by interionic hydrogen bonds and coulombic interactions of molecular ions.

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  1. Institute of Physiologically Active Substances, Russian Academy of Sciences, Chernogolovka, Russia

    A. N. Chekhlov

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  1. A. N. Chekhlov
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Chekhlov, A.N. Crystal Structure of 1,10-Diazonia-18-crown-6 Bis(DL-glutamate). Russian Journal of General Chemistry 71, 109–113 (2001). https://doi.org/10.1023/A:1012345809898

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