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Vinyl Ethers Containing an Isothiocyanato Group: XVII. Bis-Acetals Containing Isothiocyanato Groups on the Basis of Aromatic Diols

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Abstract

2-Vinyloxyethyl isothiocyanate reacts with aromatic diols: catechol, resorcinol, hydroquinone, 2,3-dihydroxynaphthalene, and 2,2-bis(p-hydroxyphenyl)propane, in the presence of 0.25-0.5 wt % of trifluoroacetic acid (55-80°C, 0.5-2 h) to give bis-acetals containing isothiocyanato groups in quantitative yield.

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Tolmachev, S.V., Zinov'eva, V.P., Sarapulova, G.I. et al. Vinyl Ethers Containing an Isothiocyanato Group: XVII. Bis-Acetals Containing Isothiocyanato Groups on the Basis of Aromatic Diols. Russian Journal of Organic Chemistry 37, 1–4 (2001). https://doi.org/10.1023/A:1012316011039

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