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Ozonolysis of Alkenes and Studies of Reactions of Polyfunctional Compounds: LXV. Ozonolysis of Perfluoro-1-octene in Freon-113

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Abstract

Ozonization of perfluoro-1-octene in Freon-113 yields the corresponding ozonide whose catalytic hydrogenation over Pd/C or hydride reduction leads to formation of perfluoroheptanoic acid; the reduction with lithium aluminum hydride gives 2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-1-heptanol. Ozonization of perfluoro-1-octene in Freon-113 containing excess (≥3 equiv) alcohol affords the corresponding perfluoroheptanoic acid ester.

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Authors and Affiliations

  1. Academy of Sciences of Bashkortostan Republic and Ufa Research Center of the Russian Academy of Sciences, Institute of Petroleum Chemistry and Catalysis, pr. Oktyabrya 141, Ufa, 450075, Bashkortostan, Russia

    V. N. Odinokov, V. R. Akhmetova, M. V. Bazunova, R. G. Savchenko, E. A. Paramonov & L. M. Khalilov

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  1. V. N. Odinokov
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  2. V. R. Akhmetova
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  3. M. V. Bazunova
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  4. R. G. Savchenko
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  5. E. A. Paramonov
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  6. L. M. Khalilov
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Odinokov, V.N., Akhmetova, V.R., Bazunova, M.V. et al. Ozonolysis of Alkenes and Studies of Reactions of Polyfunctional Compounds: LXV. Ozonolysis of Perfluoro-1-octene in Freon-113. Russian Journal of Organic Chemistry 37, 321–325 (2001). https://doi.org/10.1023/A:1012311903712

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  • DOI: https://doi.org/10.1023/A:1012311903712

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