Skip to main content
Log in

Photo-Degradation of Some Dyes using Ag-Loaded Titaniumdioxide

  • Published:
Water, Air, and Soil Pollution Aims and scope Submit manuscript

Abstract

The photocatalytic degradation of organic dyes using TiO2 andsilver-loaded TiO2 has beenstudied. The dyes which were chosen (methyl violet, a cationicdye; Cibacron Blue FMR, areactive dye; and Maxilon Red GRL, a mono azo basic dye)represent the major structuralfamilies of organic dyes. Ag-loading dramatically reduceddegradation time. While theundoped TiO2 degraded about 63% of the total amount ofmethyl violet within 4 min,degradation rose to 95% with Ag-loaded TiO2 within the sametime period. The photo-decomposition of dyes was monitored as a function of pH anddissolved organic and inorganic matters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Correia, V. M., Stephenson, T. and Judd, S. J.: 1994, ‘Characterisation of Textile Wastewaters: A Review’, Environmental Technology 15, 917–929.

    Google Scholar 

  • Fox, M. A. and Dulay, M. T.: 1993, ‘Heterogeneous Photocatalysis’, Chemical Rev. 93, 341–357.

    Google Scholar 

  • Goswami, D. Y.: 1997, ‘A Review of Engineering Developments of Aqueous Phase Solar Photocatalytic Detoxification and Disinfection Processes’, Solar Energy Engineering 119, 101–107.

    Google Scholar 

  • Hoffmann, M. R., Martin, S. T., Choi, W. and Bahnemann, D.W.: 1995, ‘Environmental Applications of Semiconductors Photocatalysis’, Chemical Rev. 95, 69–96.

    Google Scholar 

  • Kamat, P. V.: 1993, ‘Photochemistry on Nonreactive and Reactive (Semiconductor) Surfaces’, Chemical Rev. 93, 267–300.

    Google Scholar 

  • Kondo, M. and Jardim, W.: 1991, ‘Photodegradation of Chloroform and Urea Using Ag-Loaded Titanium Dioxide as Catalyst’, Water Res. 25, 823–827.

    Google Scholar 

  • Ku, Y. and Hsieh, C.-B.: 1992, ‘Photocatalytic Decomposition of 2,4-Dichlorophenol in Aqueous TiO2 Suspensions’, Water Research 26, 1451–1456.

    Google Scholar 

  • Kutsuna, S., Toma, M., Takeuchi, K. and Ibusuki, T.: 1999, ‘Photocatalytic Degradation of Some Perfluoroalkyl Ethers on the Dark-Adsoption, the Products, and the Implication for a Possible Tropospheric Sink’, Environ. Sci. Technol. 33, 1071–1076.

    Google Scholar 

  • Legrini, O., Oliveros, E. and Braun, A. M.: 1993, ‘Photochemical Processes for Water Treatment’, Chemical Rev. 93, 671–698.

    Google Scholar 

  • Linsebigler, A. L., Guangquan, L. and Yates Jr., J. T.: 1995, ‘Photocatalysis on TiO2 Surfaces’, Chemical Rev. 95, 735–758.

    Google Scholar 

  • Ollis, D. F., Pelizzetti, E. and Serpone, N.: 1991, ‘Destruction of Water Contaminants’, Environ. Sci. Technol. 25, 1523–1529.

    Google Scholar 

  • Tennakone, K., Punchihewa, S., Wickremanayaka, S. and Tuntrigodda, U.: 1989, ‘Titanium Dioxide Catalysed Photo-Oxidation of Methyl Violet’, J. Photo Chem. Photo Biol. 46, 247–252.

    Google Scholar 

  • Venkatadri, R. and Peters, R. W.: 1993, ‘Chemical Oxidation Technologies: Ultraviolet Light/Hydrogen Peroxide, Fenton's Reagent, and Titanium Dioxide-Assisted Photocatalysis’, Hazardous Waste and Hazardous Materials 10, 107–149.

    Google Scholar 

  • Wu, T., Li, T., Zhao, J., Hidaka, H. and Serpone, N.: 1999, ‘TiO2-Assisted Photodegradation of Dyes. 9: Photooxidation of a Squarylium Cyanine Dye in Aqueous Dispersions under Visible Light Irradiation’, Environ. Sci. Technol. 33, 1379–1387.

    Google Scholar 

  • Zang, L., Macyk, W., Lange, C., Maier, W. F., Antonius, C., Meissner, D. and Kisch, H.: 2000, ‘Visible-Light Detoxification and Charge Generation by Transition Metal Chloride Modified Titania’, Chem. Eur. J. 6, 379–384.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Münevver Sökmen.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sökmen, M., Allen, D.W., Akkaş, F. et al. Photo-Degradation of Some Dyes using Ag-Loaded Titaniumdioxide. Water, Air, & Soil Pollution 132, 153–163 (2001). https://doi.org/10.1023/A:1012069009633

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1012069009633

Navigation