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Thermal Properties of Complexes of Mn(II), Fe(II), Co(II), Ni(II) With 2,2'-bipyridine Or 4,4'-bipyridine and Thiocyanates

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Abstract

The compounds ML2(NCS)2, (M(II)=Mn, Co), FeL2(NCS)2×2H2O, NiL3 NCS)2×3H2O (L=2,2'-bipyridine, 2-bipy) MX2(NCS)2×2H2O (M(II)=Mn, Fe; X=4,4'-bipyridine, 4-bipy) have been prepared and their IR spectra and molar conductivity studied. The thermal decomposition of the complexes was studied under non-isothermal conditions in air. During heating the hydrated complexes lose crystallization water molecules in one or two steps and then decompose via different intermediate compounds to the oxides Mn3O4, Fe2O3, CoO, NiO.

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REFERENCES

  1. M. Kabešová, J. Kohout and J. Gažo, Monatsch. Chem., 107 (1976) 641.

    Article  Google Scholar 

  2. L. Macášková, M. Kabešová, J. Garaj and J. Gažo, ibid., 104 (1973) 1473.

    Article  Google Scholar 

  3. M. Kabešová, J. Pirskij and M. Dunaj-Jurèo, J. Thermal Anal., 34 (1988) 1349.

    Article  Google Scholar 

  4. R. J. H. Clark and C. S. Williams, Spectrochim. Acta, 22 (1966) 1081.

    Article  CAS  Google Scholar 

  5. E. D. McKenzie, Coord. Chem. Rev., 6 (1971) 187.

    Article  CAS  Google Scholar 

  6. E. Joná, M. Jamnicky and T. Šramko, Z. Anorg. Allg. Chem., 447 (1978) 207.

    Article  Google Scholar 

  7. E. Joná and M. Jamnicky, J. Thermal Anal., 27 (1983) 359.

    Article  Google Scholar 

  8. E. Joná, T. Šramko and J. Gažo, ibid., 16 (1979) 213.

    Article  Google Scholar 

  9. H. Langfelderová, K. Macášková, K. Otrubová and J. Gažo, ibid., 31 (1986) 143.

    Article  Google Scholar 

  10. M. Kabešová and V. Jorik, ibid., 46 (1996) 1705.

    Article  Google Scholar 

  11. L. Erdey and G. Liptay, Periodica Polytechnica (Budapest), 7 (1963) 223.

    CAS  Google Scholar 

  12. W. W. Wentlandt and S. Iftikhar Ali, Z. Anorg. Allg. Chem., 337 (1965) 6.

    Article  Google Scholar 

  13. A. M. Golub and H. Köhler ‘Chemie der Pseudohalogenide’, VEB Deutscher Verlag der Wissenschaften, Berlin 1979.

    Google Scholar 

  14. E. König and K. Watson, J. Chem. Phys. Lett., 6 (1970) 457.

    Article  Google Scholar 

  15. P. Pfeiffer and F. Tapperman, Z. Anorg. Chem., 215 (1933) 273.

    Article  CAS  Google Scholar 

  16. I. S. Ahuja, R. Singh and C. L. Yadava, J. Mol. Struct., 74 (1981) 143.

    Article  CAS  Google Scholar 

  17. D. Czakis-Sulikowska and J. Kałużna, J. Thermal Anal., 47 (1996) 1763.

    Article  CAS  Google Scholar 

  18. D. Czakis-Sulikowska and J. Kałużna, J. Therm. Anal. Cal., 57 (1999) 51.

    Article  Google Scholar 

  19. D. Czakis-Sulikowska and J. Kałużna-Czaplińska, Polish J. Chem., 72 (1998) 2218.

    CAS  Google Scholar 

  20. D. Czakis-Sulikowska, J. KałuŌna and J. Radwańska-Doczekalska, J. Thermal Anal., 53 (1998) 103.

    Google Scholar 

  21. J. Radwańska-Doczekalska, D. Czakis-Sulikowska and M. Markiewicz, ibid., 48 (1997) 865.

    Article  Google Scholar 

  22. D. Czakis-Sulikowska and A. Malinowska, J. Therm. Anal. Cal., 51 (1998) 575.

    CAS  Google Scholar 

  23. Powder Diffraction File. International Center of Diffraction Data. ICPDS-ICDD, 1990. 1601 Park Lana Swarthmore.

  24. W. J. Geary, Coord. Chem. Rev., 7 (1971) 81.

    Article  CAS  Google Scholar 

  25. N. M. Karayannis, A. N. Speca, D. E. Chasen and L. L. Pytlewski, ibid., 20 (1976) 37.

    Article  CAS  Google Scholar 

  26. S. P. Sinha, Spectrochim. Acta, 20 (1964) 879.

    Article  CAS  Google Scholar 

  27. B. J. Hatway, I. M. Procter, R. C. Slade and A. A. G. Tomlinson, J. Chem. Soc. (A), (1969) 2219.

    Google Scholar 

  28. B. Martin, W. R. McWhinnie and G. M. Waind, J. Inorg. Nucl. Chem., 23 (1961) 207.

    Article  CAS  Google Scholar 

  29. C. K. Pearce, D. W. Grosse and W. Hessel, Chem. Eng. Data, 15 (1970) 567.

    Article  CAS  Google Scholar 

  30. A. H. Norbury, Adv. Inorg. Chem. Radiochem., 17 (1975) 231 and references cited therein.

    CAS  Google Scholar 

  31. Gmelins Handbuch der anorganischen Chemie, System No 59, Die Verbindungen des Eisens, Teil B, Verlag Chemie, GmbH, Berlin 1932.

    Google Scholar 

  32. T. P. J. Prasad, J. Thermal Anal., 34 (1988) 801, ibid., 31 (1986) 553, ibid., 35 (1989) 2539.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of General and Ecological Chemistry, Technical University, 90-924, Łódź, Poland

    D. Czakis-Sulikowska & J. Kałużna-Czaplińska

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  1. D. Czakis-Sulikowska
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  2. J. Kałużna-Czaplińska
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Czakis-Sulikowska, D., Kałużna-Czaplińska, J. Thermal Properties of Complexes of Mn(II), Fe(II), Co(II), Ni(II) With 2,2'-bipyridine Or 4,4'-bipyridine and Thiocyanates. Journal of Thermal Analysis and Calorimetry 62, 821–830 (2000). https://doi.org/10.1023/A:1012046030204

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