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Asymmetric transfer hydrogenation of ketones catalyzed by rhodium and iridium complexes with chiral bidentate Schiff's bases

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Russian Chemical Bulletin Aims and scope

Abstract

Rhodium and iridium complexes of Schiff's bases derived from (1R,2R)- and (1S,2S)-diaminocyclohexane catalyze asymmetric transfer hydrogenation of alkyl aryl ketones in PriOH at room temperature to give chiral secondary alcohols (up to 65% ee).

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119992, Moscow, Russian Federation

    V. A. Pavlov, M. G. Vinogradov, E. V. Starodubtseva, G. V. Chel"tsova, V. A. Ferapontov & O. R. Malyshev

  2. Cambrex Corporation, One Meadowlands Plaza, East Rutherford, NJ, 07073, USA

    G. L. Heise

Authors
  1. V. A. Pavlov
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  2. M. G. Vinogradov
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  3. E. V. Starodubtseva
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  4. G. V. Chel"tsova
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  5. V. A. Ferapontov
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  6. O. R. Malyshev
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  7. G. L. Heise
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Pavlov, V.A., Vinogradov, M.G., Starodubtseva, E.V. et al. Asymmetric transfer hydrogenation of ketones catalyzed by rhodium and iridium complexes with chiral bidentate Schiff's bases. Russian Chemical Bulletin 50, 734–735 (2001). https://doi.org/10.1023/A:1011393702787

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  • DOI: https://doi.org/10.1023/A:1011393702787

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