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Aminoguanidinium closo-Borates and Their Reactions with Copper(II) Salts in Aqueous Solutions

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Abstract

Aminoguanidinium hexa-, deca-, and dodecaborates of (AguH)2B n H n · xH2O (Agu = (CN4H6), n= 6, 10, 12; x= 1, 2) composition were synthesized and studied by elemental analysis, magnetic susceptibility, and IR spectroscopy methods. Their reactions with copper(II) salts in aqueous solutions were investigated. A cation–anion interaction was shown to occur in aminoguanidinium closo-borates and to increase in the series B12< B10< B6. Depending on the closo-anion (B n H2– n ), the reactions of aminoguanidinium closo-borates with copper(II) salts in aqueous solutions yield either complex compounds (n= 10, 12) or metallic copper (n= 6).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    E. A. Malinina, V. N. Mustyatsa, L. V. Goeva & N. T. Kuznetsov

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  1. E. A. Malinina
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  2. V. N. Mustyatsa
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  3. L. V. Goeva
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  4. N. T. Kuznetsov
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Malinina, E.A., Mustyatsa, V.N., Goeva, L.V. et al. Aminoguanidinium closo-Borates and Their Reactions with Copper(II) Salts in Aqueous Solutions. Russian Journal of Coordination Chemistry 27, 373–376 (2001). https://doi.org/10.1023/A:1011380622894

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  • DOI: https://doi.org/10.1023/A:1011380622894

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