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Synthesis and X-ray structure of [(H3O)(C14H20O5)2][Me2NH2]2 [PMo12O40] · 2C14H20O5 (C14H20O5 = benzo-15-crown-5; Me2NH = dimethylamine)

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Abstract

[(H3O)(C14H20O5)2][Me2NH2]2 [PMo12O40] · 2C14H20O5 1 was synthesized from benzo-15-crown-5 and H3PMo12O40·24H2O in N,N′-dimethylformamide for the first time. 1 crystallizes in the monoclinic space group C2/c with a = 18.583(4), b = 25.510(5), c = 19.904(4) Å, β = 94.66(3)° D c = 2.124 mg/m3 for Z = 4. Refinement based on 7358 observed reflections led to a R1(wR2) = 0.0378(0.0761). The complex cation, [(H3O)(C14H20O5)2]+, exhibits a sandwich structure by hydrogen-bonding in the mean distance of 2.955 Å. The anion, PMo12O40 3−, is a α-Keggin structure.

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References

  1. Izatt, R.M.; Haymore, B.L.; and Christensen., J.J. J. Chem. Soc. Chem. Commun. 1972, 1308.

  2. Atwood, J.L.; Bott, S.G.; Coleman, A.W.; Robinson, K.D.; Whetstone, S.B.; and Means, C.M. J. Am. Chem. Soc. 1987, 109, 8100.

    Google Scholar 

  3. Atwood, J.L.; Bott, S.G.; Coleman, A.W.; Zhang, H.; and May, M.T. Inorg. Chem. 1990, 29, 467.

    Google Scholar 

  4. Atwood, J.L.; Bott, S.G.; Robinson, K.D.; Bishop, E.J.; and May, M.T. J. Cryst. Spec. Res. 1991, 21, 459.

    Google Scholar 

  5. Atwood, J.L.; Junk, P.C.; May, M.T.; and Robinson, K.D.J. Chem. Crystallogr. 1994, 24, 243.

    Google Scholar 

  6. Atwood, J.L.; Bott, S.G.; Junk, P.C.; and May, M.T. J. Organomet. Chem. 1995, 487, 7.

    Google Scholar 

  7. Chènevert, R.; and Chemberland. D. Can. J. Chem. 1989, 67, 32.

    Google Scholar 

  8. Chènevert, R.; Chamberland, D. Can. J. Chem. 1990, 68, 797.

    Google Scholar 

  9. Sheldrick, G.M. SHELXTL-Plus. Structure Determination Program; Siemens Analytical X-ray Instruments Inc., Madison, WI, 1990.

    Google Scholar 

  10. Sheldrick, G.M. SHELXL93. Program for the Refinement of Crystal Structure; University of Göttingen, Germany, 1993.

    Google Scholar 

  11. Strandberg, R. Acta Chem. Scand. Ser. A. 1975, 29, 358-364.

    Google Scholar 

  12. D'amour, H.; Allmann, R. Z. Kristallogr. 1976, 143, 1-13.

    Google Scholar 

  13. Pope M.T. Heteropoly and Isopoly Oxometatalates; Springer-Verlag, Berlin/Heidelberg/New York/Tokyo, 1983, p 24.

    Google Scholar 

  14. Rogers, R.D.; Bond, A.H.; Hipple, W.G.; Rollins A.N.; Henry, R.F. Inorg. Chem. 1991, 30, 2671-2679.

    Google Scholar 

  15. Behr, J.P., Dumas, P., and Moras, D. J. Am. Chem. Soc. 1982, 104, 4540.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, Northeast Normal University, Changchun, 130024, P.R. China

    Wansheng You, Zaiming Zhu, Enbo Wang, Lin Xu & Changwen Hu

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  1. Wansheng You
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  2. Zaiming Zhu
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  3. Enbo Wang
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  4. Lin Xu
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  5. Changwen Hu
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You, W., Zhu, Z., Wang, E. et al. Synthesis and X-ray structure of [(H3O)(C14H20O5)2][Me2NH2]2 [PMo12O40] · 2C14H20O5 (C14H20O5 = benzo-15-crown-5; Me2NH = dimethylamine). Journal of Chemical Crystallography 30, 577–581 (2000). https://doi.org/10.1023/A:1011354226178

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