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Synthesis of 5H-naphtho[2,3-c]phenothiazine-8,13-diones from 1-arylthio-2-azidoanthraquinones

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Abstract

Thermolysis of 1-arylthio-2-azidoanthraquinones in DMSO at 150 °C afforded substituted 5H-naphtho[2,3-c]phenothiazine-8,13-diones. These compounds were also formed upon photolysis of azides at 77 K and were prepared in quantitative yields by the reactions of 1-arylthio-2-azidoanthraquinones with KOH in DMSO at 20 °C.

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Authors and Affiliations

  1. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent"eva, 630090, Novosibirsk, Russian Federation

    L. S. Klimenko

  2. Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 3 ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    E. A. Pritchina & N. P. Gritsan

  3. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    E. A. Pritchina & N. P. Gritsan

Authors
  1. L. S. Klimenko
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  2. E. A. Pritchina
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  3. N. P. Gritsan
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Klimenko, L.S., Pritchina, E.A. & Gritsan, N.P. Synthesis of 5H-naphtho[2,3-c]phenothiazine-8,13-diones from 1-arylthio-2-azidoanthraquinones. Russian Chemical Bulletin 50, 678–681 (2001). https://doi.org/10.1023/A:1011321114174

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