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Regularities in the Change in Coordination Number of Lanthanide in Aqueous Solutions of LnL Complexes with an Increase in the Atomic Number of the Ln3+Ion

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Abstract

A method is proposed where the values of entropy change upon formation of LnL (H2O) n and AnL (H2O) n lanthanide and actinide complexes in aqueous solutions are used to determine the coordination numbers of Ln3+and An3+and the number of coordinated water molecules in these complexes.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117915, Russia

    G. V. Ionova

  2. Commissariat à l"énergie atomique, CEA, Saclay, France

    Ch. Madic

  3. Ministre des Commerce, Paris, France

    R. Guillaumont

Authors
  1. G. V. Ionova
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  2. Ch. Madic
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  3. R. Guillaumont
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Ionova, G.V., Madic, C. & Guillaumont, R. Regularities in the Change in Coordination Number of Lanthanide in Aqueous Solutions of LnL Complexes with an Increase in the Atomic Number of the Ln3+Ion. Russian Journal of Coordination Chemistry 27, 439–442 (2001). https://doi.org/10.1023/A:1011300111507

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  • DOI: https://doi.org/10.1023/A:1011300111507

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