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Two Modifications of the Mixed-Ligand Complex ZnPhen(i-C3H7OCS2)2 with Monodentate and Bidentate Ligands i-C3H7OCS -2

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Abstract

Two crystal modifications (m-1 and m-2) of the mixed-ligand complex ZnPhen(i-PrOCS2)2 have been isolated. Their crystal structures were solved using X-ray diffraction data (CAD-4 diffractometer, MoKα radiation, 3141 and 3532 Fhkl, R = 0.0363 and 0.0304). For both modifications, the crystals are monoclinic with unit cell parameters a = 10.543(2), b = 13.494(3), c = 16.875(3) Å, β = 102.08(3)°, V = 2347.6(8) Å3, Z = 4, space group P21/n (m-1) and a = 10.931(2), b = 12.996(3), c = 16.288(3) Å, β = 92.69(3)°, V = 2311.3(8) Å3, Z = 4, space group P21/n (m-2). The structures basically consist of discrete monomer molecules in which the Zn atom has a tetragonal pyramidal (m-1: ZnN2S3, c.n. 5, bidentate and monodentate i-PrOCS -2 ligands) or distorted octahedral (m-2: ZnN2S4, c.n. 6, bidentate i-PrOCS -2 ligands) environment. Molecular packings and their interactions in the structures are discussed.

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References

  1. R. F. Klevtsova, L. A. Glinskaya, S. M. Zemskova, and S. V. Larionov, Polyhedron, 18, No. 26, 3559-3565 (1999).

    Google Scholar 

  2. S. M. Zemskova, L. A. Glinskaya, V. B. Durasov, et al., Zh. Strukt. Khim., 34, No. 5, 157-166 (1993).

    Google Scholar 

  3. L. A. Glinskaya, R. F. Klevtsova, E. I. Berus, et al., ibid., 39, No. 4, 688-697 (1998).

    Google Scholar 

  4. S. V. Larionov, R. F. Klevtsova, S. M. Zemskova, amd L. A. Glinskaya, Khim. Int. Ust. Razv., 7, No. 4, 451-461 (1999).

    Google Scholar 

  5. T. G. Leonova, V. N. Kirichenko, L. A. Glinskaya, et al., Koordinats. Khim., 23, No. 8, 590-595 (1997).

    Google Scholar 

  6. G. M. Sheldrick, SHELX-97, Release 97-2, University of Göttingen, Germany (1998).

    Google Scholar 

  7. L. A. Glinskaya, R. F. Klevtsova, T. G. Leonova, and S. V. Larionov, Zh. Strukt. Khim., 41, No. 1, 196-201 (2000).

    Google Scholar 

  8. F. H. Allen, S. Bellard, M. D. Brice, et al., Acta Crystallogr., B35, 2331-2339 (1979).

    Google Scholar 

  9. S. M. Zemskova, L. A. Glinskaya, R. F. Klevtsova, et al., Zh. Strukt. Khim., 36, No. 3, 528-540 (1995).

    Google Scholar 

  10. C. A. Hunter and J. K. M. Sanders, J. Am. Chem. Soc., 112, 5525-5534 (1990).

    Google Scholar 

  11. S. V. Larionov, R. F. Klevtsova, V. G. Shchukin, et al., Koordinats. Khim., 25, No. 10, 743-749 (1999).

    Google Scholar 

  12. L. A. Glinskaya, R. F. Klevtsova, V. G. Shchukin, and S. V. Larionov, Zh. Strukt. Khim., 41, No. 1, 191-195 (2000).

    Google Scholar 

  13. S. V. Larionov, A. A. Voityuk, L. N. Mazalov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 5, 998-1002 (1981).

    Google Scholar 

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Authors and Affiliations

  1. Siberian Branch, Russian Academy of Sciences, Institute of Inorganic Chemistry, Russia

    R. F. Klevtsova, L. A. Glinskaya, T. G. Leonova & S. V. Larionov

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  1. R. F. Klevtsova
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  2. L. A. Glinskaya
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  3. T. G. Leonova
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  4. S. V. Larionov
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Klevtsova, R.F., Glinskaya, L.A., Leonova, T.G. et al. Two Modifications of the Mixed-Ligand Complex ZnPhen(i-C3H7OCS2)2 with Monodentate and Bidentate Ligands i-C3H7OCS -2 . Journal of Structural Chemistry 42, 244–250 (2001). https://doi.org/10.1023/A:1010507100297

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