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Mechanism of the Reaction of Xenon Tetraoxide with Hydrogen: A Photochemical Reaction

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Abstract

The dependence of the rate of a photochemical reaction of XeO4with H2on the concentrations of H2and the diluent gases He and CO2is studied at room temperature. The results are compared with the data for the dark reaction. A mechanism with the elementary energetic branched-chain reaction OH\({\dot H}\)(v) + XeO4→OH\({\dot H}\) + O\({\dot H}\) + XeO3is proposed to explain the results of the study.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    N. N. Aleinikov, G. K. Vasil'ev, S. A. Kashtanov, E. F. Makarov & Yu. A. Chernyshev

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  1. N. N. Aleinikov
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  2. G. K. Vasil'ev
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  3. S. A. Kashtanov
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  4. E. F. Makarov
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  5. Yu. A. Chernyshev
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Aleinikov, N.N., Vasil'ev, G.K., Kashtanov, S.A. et al. Mechanism of the Reaction of Xenon Tetraoxide with Hydrogen: A Photochemical Reaction. Kinetics and Catalysis 42, 233–237 (2001). https://doi.org/10.1023/A:1010469418851

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