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Structural Characterization of Yttrium-Implanted Pure Iron and Steels Oxidized at High Temperature

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Abstract

Yttrium-implanted and unimplanted pure electrolytic iron, low-manganese and low-manganese–carbon steels were analyzed at high temperature (T=700°C) under oxygen partial pressure \({\text{P}}_{O_2 } = 0.04Pa\) to observe their oxidation resistances. X-ray diffraction (XRD), reflected high-energy electron diffraction (RHEED), and glancing-angle X-ray diffraction (GAXRD) analyses performed on yttrium-implanted samples before high-temperature oxidation tests show that yttrium implantation promotes the formation of Y_2O_3, and yttrium–iron mixed oxides (i.e., FeYO_3 and Y_3Fe_5O_1_2) whatever the sample nature and <math>Mn_3O_4 and YMnFeO_4, in the case of samples containing manganese. In situ, high-temperature X-ray analyses allow the observation of the main compounds grown on yttrium-implanted and unimplanted samples during oxidation test at high temperature. The aim of this paper is to show that FeYO_3 andFe_2YO_4 , in the case of pure iron, and YMnO_3, in the case of steels, seem to be responsible for the improved corrosion resistance at high temperature.

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  1. Laboratoire Vellave d'Elaboration et d'Etude des Matériaux, Equipe Locale Université Blaise Pascal Clermont-Fd II, B.P. 219, 43006, Le Puy en Velay, France

    E. Caudron & H. Buscail

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  1. E. Caudron
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  2. H. Buscail
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Caudron, E., Buscail, H. Structural Characterization of Yttrium-Implanted Pure Iron and Steels Oxidized at High Temperature. Oxidation of Metals 55, 261–272 (2001). https://doi.org/10.1023/A:1010308126934

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