Skip to main content
SpringerLink
Log in

Studies on Energetic (Non) Compounds. Part 21: Preparation and thermal decomposition of ring substituted dimethyl anilinium bromides

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Six isomeric dimethyl anilinium bromides (DMABr) have been prepared and characterized by elemental and spectroscopic studies. Thermal decomposition of these salts has been studied by TG and simultaneous TG-DTA techniques. Kinetic parameters have been evaluated from isothermal TG data using contracting area and contracting cube equations. The decomposition pathways have also been suggested which involves simultaneous sublimation (at lower temperature) and dissociative vaporization/decomposition (at higher temperature).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. R. Rodebush and J. C. Michaleks, J. Am. Chem. Soc., 5 (1929) 748.

    Article  Google Scholar 

  2. M. M. Markowitz and D. A. Boryta, J. Phys. Chem., 66 (1962) 1477.

    CAS  Google Scholar 

  3. J. L. Mack and G. B. Wilmot, J. Phys. Chem., 71 (1967) 2155.

    CAS  Google Scholar 

  4. L. Erdey, Periodica Polytech., 1 (1957) 91.

    CAS  Google Scholar 

  5. L. Erdey and S. Gál, Talanta, 10 (1963) 23.

    Article  CAS  Google Scholar 

  6. L. Erdey, S. Gál and G. Liptay, Talanta, 11 (1964) 913.

    Article  CAS  Google Scholar 

  7. G. Singh and I. P. S. Kapoor, J. Chem. Soc., Perkin Trans II, (1989) 2155.

  8. G. Singh, I. P. S. Kapoor and M. Jain, J. Chem. Soc., Perkin Trans II, (1993) 1521.

  9. G. Singh, I. P. S. Kapoor and M Jain, Indian J. Chem., 35 B (1996) 369.

    Google Scholar 

  10. G. Singh, I. P. S. Kapoor and M. Jain, Thermochim. Acta, 292 (1997) 135.

    Article  CAS  Google Scholar 

  11. G. Singh, I. P. S. Kapoor and J. Singh, Indian J. Chem., 36 B (1997) 590.

    Google Scholar 

  12. G. Singh, I. P. S. Kapoor and J. Singh, Indian J. Eng. Mat. Sci.,5 (1998) 334.

    CAS  Google Scholar 

  13. G. Singh and I. P. S. Kapoor, Combust and Flame, 92 (1993) 283.

    Article  CAS  Google Scholar 

  14. G. Singh, I. P. S. Kapoor, S. M. Mannan and J. P. Agrawal, Combust and Flame, 97 (1994) 355.

    Article  CAS  Google Scholar 

  15. G. Singh and I. P. S. Kapoor, J. Phys. Chem., 96 (1992) 1215.

    Article  CAS  Google Scholar 

  16. G. Singh, I. P. S. Kapoor and S. M. Mannan, J. Thermal Anal., 46 (1996) 1751.

    Article  CAS  Google Scholar 

  17. G. Singh, I. P. S. Kapoor and J. Kaur, Indian J. Chem., 38 B (1999) 56.

    Google Scholar 

  18. G. Singh, I. P. S. Kapoor and J. Kaur, Thermochim. Acta, 35 (1999) 45.

    Article  Google Scholar 

  19. G. Singh and R. R. Singh, Res. Ind., 23 (1978) 92.

    CAS  Google Scholar 

  20. V. Satava, Thermochim. Acta, 2 (1971) 423.

    Article  CAS  Google Scholar 

  21. C. M. Wyandt and D. R. Flanagan, Thermochim. Acta, 196 (1992) 379.

    Article  CAS  Google Scholar 

  22. G. A. Heath and J. R. Majer, Trans. Faraday Soc., 60 (1964) 178.

    Article  Google Scholar 

  23. M. H. Cassel and I. Libman, J. Chem. Phys., 34 (1961) 343.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, D.D.U. Gorakhpur University, Gorakhpur, 273 009, India

    G. Singh, I. P. Singh Kapoor & J. Kaur

Authors
  1. G. Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. P. Singh Kapoor
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Kaur
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Singh, G., Singh Kapoor, I.P. & Kaur, J. Studies on Energetic (Non) Compounds. Part 21: Preparation and thermal decomposition of ring substituted dimethyl anilinium bromides. Journal of Thermal Analysis and Calorimetry 62, 305–315 (2000). https://doi.org/10.1023/A:1010199720030

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010199720030

Search

Navigation