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Synthesis, Identification and Thermal Decomposition of Double Sulfates of Mn, Cu and Cd with Benzylammonium

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Abstract

On evaporation of an aqueous mixture of M(II) sulfate (M(II) = Mn, Co, Ni, Cu, Zn or Cd) and benzylammonium sulfate in a molar ratio of 1:2 at room temperature in the presence of sulphuric acid, double sulfates of only Mn, Cu and Cd were obtained. The stoichiometries of the compounds were determined by means of elemental and TG analysis. It was concluded that these compounds have the same general formula: M(C6 H5 CH2 NH3 )2 (SO4 )2 ×4H2 O. These compounds have the same stoichiometry as that of the corresponding double sulfates with ethanolammonium cation, but have different crystal structures.

The thermal decompositions of the investigated compounds in the temperature range from ambient temperature up to 1000°C take place in a similar way, in three well-differentiated stages, but with different pathways in the second and third stages. Metal oxides were obtained as final products.

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References

  1. V. N. Serezhkin, Koord. Khim., 10 (1984) 20.

    CAS  Google Scholar 

  2. E. N. Maslen, K. J. Watson and F. N. Moore, Acta Crystallogr., 44B (1988) 102.

    Google Scholar 

  3. C. Malard, Bull. Soc. Chim. Fr., 3 (1961) 2296.

    Google Scholar 

  4. C. Duval, Thermogravimetric Analysis 2nd ed., Elsevier, Amsterdam 1963.

    Google Scholar 

  5. B. Lorand, Z. Anal. Chem., 219 (1966) 256.

    Article  Google Scholar 

  6. K. C. Patil, S. Govindaraja and H. Manohal, Synth. React. Inorg. Met. Org. Chem., 11 (1981) 245.

    CAS  Google Scholar 

  7. C. K. Prout and H. M. Powell, J. Chem. Soc., (1961) 4177.

  8. W. W. Wendlandt and G. W. Gwing, Anal. Chim. Acta, 22 (1960) 497.

    Article  CAS  Google Scholar 

  9. S. Aleksovska and V. Jordanovska, Bull. Chem. Technol. Macedonia, 9 (1990) 21.

    CAS  Google Scholar 

  10. V. Jordanovska, S. Aleksovska and J. Šiftar, J. Thermal Anal., 38 (1992) 1563.

    Article  CAS  Google Scholar 

  11. V. Jordanovska and S. Gjurevska, Trudovi. X. Sovetuvanje Hem. Tehnol. Makedonija, (1987) 165.

  12. S. Aleksovska and V. Jordanovska, Thermochim. Acta, 228 (1993) 103.

    Article  CAS  Google Scholar 

  13. V. Jordanovska and R. Trojko, Thermochim. Acta, 228 (1993) 231.

    Article  CAS  Google Scholar 

  14. V. Petruševski and S. Aleksovska, Croat. Chem. Acta, 64 (1991) 577.

    Google Scholar 

  15. R. D. Shannon and C. T. Prewitt, Acta Cryst., B25 (1969) 925.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Institute of Chemistry, Faculty of Science, 'Sv. Kiril I Metodij' University, P. O. Box 162, MK-91001, Skopje, Macedonia

    V. Jordanovska & P. Naumov

  2. Faculty of Chemistry, Plovdiv University 'Paisii Hilendarski', 4025, Plovdiv, Bulgaria

    B. Boyanov

Authors
  1. V. Jordanovska
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  2. B. Boyanov
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  3. P. Naumov
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Jordanovska, V., Boyanov, B. & Naumov, P. Synthesis, Identification and Thermal Decomposition of Double Sulfates of Mn, Cu and Cd with Benzylammonium. Journal of Thermal Analysis and Calorimetry 62, 267–275 (2000). https://doi.org/10.1023/A:1010191518212

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  • DOI: https://doi.org/10.1023/A:1010191518212

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