Skip to main content
Log in

From Precursors to Thin Films - Thermoanalytical Techniques in the Thin Film Technology

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Processing thin films for advanced applications, for instance in electronics and optoelectronics, involves several steps starting from precursor synthesis and ending up with the devices. Especially when optimizing the first steps of this chain of processes, thermoanalytical techniques play an important role. The review will focus on the main chemical deposition methods (CVD, ALE, spray pyrolysis, sol-gel) giving selected examples of problem-solving by thermal analysis. The techniques discussed are TG, DTA/DSC, EGA and their combinations. High-temperature X-ray diffraction (HTXRD) is also a powerful tool for in situ studies of thin films. The examples are taken from solar cell, superconductor and flat panel electroluminescent display technologies.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. Le Chatelier, Bull. Soc. Fr. Minér., 10 (1887) 204

    Google Scholar 

  2. K. Honda, Sci. Rep. Tohôku Univ., 4 (1915) 97.

    CAS  Google Scholar 

  3. M. Leskelä, T. Leskelä and L. Niinistö, J. Thermal Anal., 40 (1993) 1077.

    Google Scholar 

  4. P. K. Gallagher, J. Therm. Anal., 38 (1992) 17.

    Article  CAS  Google Scholar 

  5. L. Niinistö and M. Karppinen, J. Thermal Anal., 35 (1989) 319.

    Article  Google Scholar 

  6. M. Karppinen, A. Fukuoka, L. Niinistö and H. Yamauchi, Supercond. Sci. Technol., 8 (1995) 1.

    Article  Google Scholar 

  7. M. Karppinen, L. Niinistö and H. Yamauchi, J. Thermal Anal., 48 (1997) 1123.

    Article  CAS  Google Scholar 

  8. L. Niinistö, Thermal Analysis, in: Analytical Chemistry, edited by R. Kellner, J.-M. Mermet, M. Otto, H.M. Widmer, Wiley-VCH, Weinheim 1998, pp. 339–359.

    Google Scholar 

  9. M. Yoshimura, J. Mater. Res., 13 (1998) 796.

    CAS  Google Scholar 

  10. M. L. Hitchman and K. F. Jensen (Eds.), Chemical Vapor Deposition, Principles and Applications, Academic Press, London 1993.

    Google Scholar 

  11. T. Suntola, In: Handbook of Crystal Growth, vol. 3, edited by D. T. J. Hurle, Elsevier, Amsterdam 1994, pp. 601–663.

    Google Scholar 

  12. L. Niinistö, Current Opinion in Sold State and Materials Science, 3 (1998) 147.

    Article  Google Scholar 

  13. P. K. Gallagher, Thermoanalytical Methods, Ch. 7 in R. W. Cahn, P. Haasen, E. J. Krämer, (Eds.), Materials Science and Technology, A Comprehensive Treatment, Vol. 2A, VCH Publishers Inc., Weinheim 1992.

    Google Scholar 

  14. V. Balek, J. Fusek, O. Kriz, M. Leskelä, L. Niinistö, E. Nykänen. J. Rantanen and P. Soininen, J. Mater. Res., 9 (1994) 119.

    CAS  Google Scholar 

  15. Y. Sawada and M. Suzuki, Thermochim. Acta, 254 (1995) 261.

    Article  CAS  Google Scholar 

  16. L. Niinistö, Ann. Chim. (Rome), 87 (1997) 221.

    Google Scholar 

  17. M. Tiitta and L. Niinistö, Chem. Vap. Deposition, 3 (1997) 167.

    Article  CAS  Google Scholar 

  18. T. Leskelä, K. Vasama, G. Härkönen, P. Sarkio and M. Lounasmaa, Adv. Mater. Opt. Electr., 6 (1996) 169.

    Article  Google Scholar 

  19. M. Leskelä, L. Niinistö, E. Nykänen, P. Soininen and M. Tiitta, Thermochim. Acta, 175 (1991) 91.

    Article  Google Scholar 

  20. M. Tiitta, M. Leskelä, E. Nykänen, P. Soininen and L. Niinistö, Thermochim. Acta, 256 (1995) 47.

    Article  CAS  Google Scholar 

  21. L. Hiltunen, M. Leskelä, M. Mäkelä and L. Niinistö, Acta Chem. Scand., Ser. A 41 (1987) 548.

    Article  Google Scholar 

  22. A. Kareiva, M. Karppinen and L. Niinistö, J. Mater. Chem., 4 (1994) 1267.

    Article  CAS  Google Scholar 

  23. M. Karppinen, A. Kareiva, J. Lindén, M. Lippmaa and L. Niinistö, J. Alloys Comp., 225 (1995) 586.

    Article  CAS  Google Scholar 

  24. A. Kareiva, I. Bryntse, M. Karppinen and L. Niinistö, J. Solid State Chem., 121 (1996) 356.

    Article  CAS  Google Scholar 

  25. M. Leskelä, H. Mölsä and L. Niinistö, Supercond. Sci. Technol., 6 (1993) 627.

    Article  Google Scholar 

  26. B. J. Hinds, R. J. McNeeley, D. B. Studebaker, T. J. Marks, T. P. Hogan, J. L. Schindler, C. R. Kannewurf, X. F. Zhang and D. J. Miller, J. Mater. Res., 12 (1997) 1214.

    CAS  Google Scholar 

  27. W. Fan and L. Niinistö, Mater. Res. Bull., 29 (1994) 451.

    Article  CAS  Google Scholar 

  28. M. Karppinen, L. Niinistö and M. Véber, Acta Chem. Scand., 46 (1992) 255.

    Article  CAS  Google Scholar 

  29. T. Leskelä, M. Lippmaa, L. Niinistö and P. Soininen, Thermochim. Acta, 214 (1993) 9.

    Article  Google Scholar 

  30. M. Krunks, J. Madarász, L. Hiltunen, R. Mannonen, E. Mellikov and L. Niinistö, Acta Chem. Scand., 51 (1997) 294.

    CAS  Google Scholar 

  31. M. Krunks, T. Leskelä, R. Mannonen and L. Niinistö, J. Therm. Anal. Cal., 53 (1998) 355.

    Article  CAS  Google Scholar 

  32. M. Krunks, T. Leskelä, I. Mutikamen and L. Niinistö, J. Therm. Anal. Cal., in press.

  33. J. Madarász, T. Leskelä, J. Rautanen and L. Niinistö, J. Mater. Chem., 6 (1996) 781.

    Article  Google Scholar 

  34. T Arii, A. Kishi, Y. Kobayashi, Thermochim. Acta, 325 (1999) 151.

    Article  CAS  Google Scholar 

  35. J. Kristóf, J. Mihály, S. Daolio, A. De Battisti, L. Nanni and C. Piccirillo, J. Electroanal. Chem., 434 (1997) 99.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Niinistö, L. From Precursors to Thin Films - Thermoanalytical Techniques in the Thin Film Technology. Journal of Thermal Analysis and Calorimetry 56, 7–15 (1999). https://doi.org/10.1023/A:1010154818649

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010154818649

Navigation