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Etude du Systeme Ternaire Se-Te-Sn

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Abstract

This work is a part of the systematic study of the ternary based chalcogenides systems. The aim is to determine the phase equilibrium, and to determine the limits of the phase area. This is done in view to perfecting knowledge of elaboration conditions for new materials and to study of their physical properties.

Few works have been devoted to the study of the ternary system Se-Te-Sn, only the cross section SnSe-SnTe has been studied [1] and [2].

The experimental study by DTA, DSC and X-ray diffraction on powder performed at room temperature, exhibits a miscibility gap in the liquid state which narrows as it goes through the Sn-Se binary system.

Three cross sections behave as ‘quasi-binary‘ system and six ternary invariants have been exhibited: three ternary eutectics and three ternary quasi-peritectics.

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Authors and Affiliations

  1. Laboratoire de Chimie Physique Minérale et Bioinorganique, Faculté de Pharmacie 5, EA 401, rue J. B. Clément, 92296, Châtenay-Malabry, France

    M. Majid & B. Legendre

Authors
  1. M. Majid
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  2. B. Legendre
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Majid, M., Legendre, B. Etude du Systeme Ternaire Se-Te-Sn. Journal of Thermal Analysis and Calorimetry 54, 963–990 (1998). https://doi.org/10.1023/A:1010133129344

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  • DOI: https://doi.org/10.1023/A:1010133129344

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