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Investigation of the Chemical Interaction in the Sb2Te3–InSe System and the Properties of the Obtained Phases

  • PHYSICOCHEMICAL ANALYSIS OF INORGANIC SYSTEMS
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Abstract

The interaction in the Sb2Te3–InSe system was studied and the T–x phase diagram was constructed by integrated methods of physicochemical analysis (differential thermal, X-ray powder diffraction, and microstructural analyses) and also by microhardness and density measurements. It was found that the Sb2Se3–InSe system is a quasi-binary section of the ternary reciprocal system Sb,In||Se,Te. In the Sb2Te3–InSe system, compounds InSb2SeTe3 and In3Sb2Se3Te3 form, which incongruently melt at 525 and 600°C, respectively. It was found that the regions of solid solutions based on Sb2Te3 and InSe extend to 3 and 2 mol %, respectively. The compounds Sb2Se3 and InSe form a eutectic with the coordinates 20 mol % InSe and 510°C. The temperature dependences of the electrical conductivity and thermal emf of the solid solutions (Sb2Te3)1 – x(InSe)x (x = 0.01, 0.02, and 0.03).

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Authors and Affiliations

  1. Nagiev Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan, Az1143, Baku, Azerbaijan

    I. I. Aliev, N. A. Mamedova & I. G. Melikova

  2. Khalilov Baku State University, Az1143, Baku, Azerbaijan

    F. M. Sadygov

  3. Institute of Geology, National Academy of Sciences of Azerbaijan, Az1143, Baku, Azerbaijan

    N. M. Sadygov

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  1. I. I. Aliev
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  2. N. A. Mamedova
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  3. F. M. Sadygov
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  4. N. M. Sadygov
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  5. I. G. Melikova
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Correspondence to I. I. Aliev.

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Translated by V. Glyanchenko

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Aliev, I.I., Mamedova, N.A., Sadygov, F.M. et al. Investigation of the Chemical Interaction in the Sb2Te3–InSe System and the Properties of the Obtained Phases. Russ. J. Inorg. Chem. 65, 1585–1590 (2020). https://doi.org/10.1134/S0036023620100010

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  • DOI: https://doi.org/10.1134/S0036023620100010

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