Skip to main content
SpringerLink
Log in

Study of Heterogeneous Properties of Solids by Means of a Special Thermal Analysis Technique

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Thermogravimetry (TG) was successfully applied in order to study the heterogeneous properties of solid surfaces and adsorbed liquid films. The method utilized the thermogravimetric mass-loss Q-TG and differential Q-DTG curves with respect to temperature and time for the desorption of liquidus from solid surfaces under quasi-isothermal conditions. Evaluation of the experimental data revealed the heterogeneous properties of the tested samples. It appears that this modern special TG technique is very useful for the study of liquid/solid systems and can be competitive with traditional techniques because of the speed and accuracy with which the data are obtained and the simplicity of the experimental operations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. S. Gregg and K. S. W. Sing, Adsorption, Surface Area and Porosity, Academic Press, New York 1967.

    Google Scholar 

  2. W. Rudziński and D. H. Everett, Adsorption of Gases on Heterogeneous Surfaces, Academic Press, London 1992.

    Google Scholar 

  3. P. Staszczuk, Powder Technol., 34 (1983) 161; 35 (1983) 97.

    Article  CAS  Google Scholar 

  4. P. Staszczuk, J. Thermal Anal., 29 (1984) 217.

    CAS  Google Scholar 

  5. P. Staszczuk, Habilitation Thesis, UMCS Lublin, 1987.

  6. P. Staszczuk, Thermochim. Acta, 247 (1994) 169.

    Article  CAS  Google Scholar 

  7. L. Erdey, F. Paulik and J. Paulik, Hungarian Patent No 152197, 1962, patents in USA, UK, Germany, Switzerland, Austria, Italy and France.

  8. F. Paulik, Special Trends in Thermal Analysis, J. Wiley & Sons, Chichester, 1995.

    Google Scholar 

  9. F. Paulik and J. Paulik, Hungarian Patent No 163.305, 1976, patents in USA, UK, Germany, Switzerland, Austria, Italy, France and Japan.

  10. J. Simon, J. Thermal Anal., 4 (1972) 205.

    Article  CAS  Google Scholar 

  11. W. W. Wendlandt, Thermal Methods of Analysis, J. Wiley & Sons, Inc., New York 1974.

    Google Scholar 

  12. B. Wunderlich, Thermal Analysis, Academic Press, Boston 1990.

    Google Scholar 

  13. P. Staszczuk, R. Dobrowolski and M. Jaroniec, Langmuir, 8 (1992) 229.

    Article  CAS  Google Scholar 

  14. P. Staszczuk, M. Jaroniec and R. K. Gilpin, Anal. Chim. Acta, 269 (1992) 157.

    Article  CAS  Google Scholar 

  15. J. Goworek, W. Stefaniak and A. Dąbrowski, Thermochim. Acta, 259 (1995) 87.

    Article  CAS  Google Scholar 

  16. J. Goworek and W. Stefaniak, J. Thermal Anal., 45 (1995) 999.

    CAS  Google Scholar 

  17. B. Hunger, M. V. Szombathely, J. Hoffmann and P. Brauer, J. Thermal Anal., 44 (1995) 293.

    CAS  Google Scholar 

  18. V. Dondur and D. Vucelic, Thermochim. Acta, 68 (1983) 91, 101, 113.

    Article  CAS  Google Scholar 

  19. J. Goworek and W. Stefaniak, Colloids and Surfaces, 54 (1991) 325; 54 (1991) 329; 57 (1991) 161; 60 (1991) 341; 62 (1991) 135; 69 (1992) 23; 82 (1994) 71.

    Google Scholar 

  20. J. Goworek and W. Stefaniak, Wiad. Chem., 46 (1992) 863.

    CAS  Google Scholar 

  21. J. Goworek and W. Stefaniak, Faculty of Chemistry, Maria Curie-Skłodowska University Report, 1997 pp. 101-102.

  22. J. Goworek, Am. Lab., 5 (1995) 16.

    Google Scholar 

  23. J. Goworek, W. Stefaniak and A. Świątkowski, Abstracts: 2nd International Conference on Carbon Black, Mulhouse, France, 1993, p. 91.

  24. E. Kozak, W. Stefaniak, J. Goworek, Z. Sokolowska and S. Sokolowski, Journal of Porous Materials, 4 (1997) 45.

    Article  CAS  Google Scholar 

  25. Z. Hubicki, J. Goworek and W. Stefaniak, Bulletin of the Polish Academy of Sciences Chemistry, 45 (1997) 169.

    Google Scholar 

  26. P. Staszczuk, Colloids and Surfaces A: Physicochem. and Eng. Aspects, 105 (1995) 291.

    Article  CAS  Google Scholar 

  27. P. Staszczuk, J. Thermal Anal., 46 (1996) 1821.

    Article  CAS  Google Scholar 

  28. P. Staszczuk, Am. Lab., 28(12) (1996) 21.

    CAS  Google Scholar 

  29. V. I. Bogillo and P. Staszczuk, J. Therm. Anal. Cal., 55 (1999) 493.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Physicochemistry of Solid Surfaces, Institute of Physical Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, M. Curie-Skłodowska Sq, 3 20-031, Lublin, Poland

    P. Staszczuk & D. Głażewski

Authors
  1. P. Staszczuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. Głażewski
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Staszczuk, P., Głażewski, D. Study of Heterogeneous Properties of Solids by Means of a Special Thermal Analysis Technique. Journal of Thermal Analysis and Calorimetry 55, 467–481 (1999). https://doi.org/10.1023/A:1010119719085

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010119719085

Search

Navigation