Abstract
Crystal of the complex Ni2L (ClO4)2 was obtained by reaction of Ni(ClO4)2 and macrocyclic ligand H2L, where L2− is the dinucleating macrocycle with two 2,6-di(aminomethyl)-4-methyl phenolate entities combined by the same two lateral chains, –(CH2)2–NH–(CH2)2–, at the amino nitrogens. The thermal decomposition processes of the title complex were studied in a dynamic atmosphere of dry argon using TG-DTG. The kinetic analysis of the first and second thermal decomposition steps were performed via the TG-DTG curves, and the kinetic parameters were obtained from analysis of the TG-DTG curves with integral and differential methods. The most probable kinetic function was suggested by comparison of the kinetic parameters.
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Yan, W., Ma, C., Wu, J. et al. Synthesis and Thermal Decomposition of the Macrocyclic Dinuclear Ni(II) Complex. Journal of Thermal Analysis and Calorimetry 58, 393–401 (1999). https://doi.org/10.1023/A:1010111406937
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DOI: https://doi.org/10.1023/A:1010111406937