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Calcul Des Diagrammes De Phases Des Systemes Binaires H2O–MCln (M=Mg2+, Fe2+, Fe3+)

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Abstract

A semi-empirical model consistent with thermodynamical conditions of equilibrium was used and oriented to the calculation of phase diagrams of the binary systems H2 O-MgCl2 , H2 O-FeCl2 and H2 O-FeCl3 . For each solid phase, the exploitation of the experimental and bibliographical data gives a liquidus curve equation comprising a limited number of parameters. A such equation allows to calculate with precision the solubility of the stoichiometric solid phase in a large range of temperature and composition.

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Authors and Affiliations

  1. Laboratoire de Chimie Minérale Appliquée et Génie des Procédés, Faculté des Sciences, Université Ibn Zohr, B. P. 28/S, Agadir, Maroc

    A. Atbir, A. Marrouche, H. Atif, L. Boukbir & M. El Hadek

  2. Physico-chimie Minérale II, Laboratoire de Physico-chimie des Matériaux Luminescents URA 442, Université Claude Bernard Lyon I, France

    R. Cohen-Adad

Authors
  1. A. Atbir
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  2. A. Marrouche
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  3. H. Atif
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  4. L. Boukbir
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  5. M. El Hadek
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  6. R. Cohen-Adad
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Atbir, A., Marrouche, A., Atif, H. et al. Calcul Des Diagrammes De Phases Des Systemes Binaires H2O–MCln (M=Mg2+, Fe2+, Fe3+). Journal of Thermal Analysis and Calorimetry 61, 849–860 (2000). https://doi.org/10.1023/A:1010109500891

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