Abstract
The electrical conductivity and thermoelectric power of Mn-doped BaTiO3 (1 mole%) and “undoped” BaTiO3 have been measured as functions of oxygen partial pressure (in the range of 10-16 to 1 atm) and temperatures (in the range of 900 to 1200°C), and compared with each other to differentiate the effect of the Mn-addition. It is found that the isothermal conductivity of Mn-doped BaTiO3 varies with increasing Po2 as σ ∝ \(Po_2^{ - 1/4} \) to ∝ \({\text{Po}}_2^{ - 1/6} \) to ∝ \({\text{Po}}_2^{ + 1/6} \) , unlike previously reported. This behavior is well explained by the shift of the ionization equilibrium, \({\text{Mn}}_{Ti}^x \). The corresponding equilibrium constant, KA, is determined from the Po2 values demarcating those three different Po2 regions as \(K_A /{\text{cm}}^{ - 3} \) =3.19×1022 exp(−1.69 eV/kT). Basic parameters involving carrier density and mobility, and defect structure of Mn-doped BaTiO3 are discussed in comparison with those of undoped BaTiO3.
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M. Matsuoka, Y. Matsuo, H. Sasaki, and S. Hayagawa, J. Am. Ceram. Soc., 55[2], 108 (1972).
H. Ueoka, Ferroelectrics, 7, 352–53 (1974).
H.-J. Hagemann and H. Ihrig, Phys. Rev. B, 20[9], 3871–3878 (1979).
H. Ihrig, J. Am. Ceram. Soc., 64[10], 617–620 (1981).
T.R.N. Kutty and P. Murugarai, Mater. Lett., 3[5–6], 195–198 (1985).
C.-J. Ting, C.-J. Peng, H.-Y. Lu, and S.-T. Wu, J. Am. Ceram. Soc., 73[20], 329–334 (1990).
S.B. Desu and E.C. Subbarao, pp. 189–206 in Advances in Ceramics, Vol. 1, Grain Boundary Phenomena in Electronic Ceramics, ed. by L.M. Levinson, Am. Ceram. Soc., (Columbus, Ohio, 1981).
H.J. Hagemann and D. Hennings, J. Am. Ceram. Soc., 64[10], 590–594 (1981).
S. Osawa, A. Furuzawa, and N. Fujikawa, J. Am. Ceram. Soc., 76[5], 1191–1194 (1993).
H.-I. Yoo and J.-H. Hwang, J. Phys. Chem. Solids, 53[7], 973–981 (1992).
S.A. Long and R.N. Blumenthal, J. Am. Ceram. Soc., 54[10], 515–519 (1971).
A.M.J.H. Seuter, Philips Res. Repts. Suppl., 3, 1–81 (1974).
J. Daniels and K.H. Härdtl, Philips Res. Repts., 31, 489–504 (1976).
N.H. Chan and D.M. Smyth, J. Electrochem. Soc., 123[10], 1584–1585 (1976).
N.G. Eror and D.M. Smyth, J. Solid State Chem., 24, 235–244 (1978).
N.H. Chan, R.K. Sharma, and D.M. Smyth, J. Am. Ceram. Soc., 64[9], 556–562 (1981).
J. Daniels, Philips Res. Repts., 31, 505–515 (1976).
N.-H. Chan, R.K. Sharma, and D.M. Smyth, J. Am. Ceram. Soc., 65[3], 167–170 (1982).
Y.H. Han, J.B. Appleby, and D.M. Smyth, J. Am. Ceram. Soc., 70[2], 96–100 (1987).
H. Ikushima and S. Hayakawa, J. Phys. Soc. Japan, 19, 1986 (1964).
H.-I. Yoo and C.-S. Kim, Solid State Ionics, 53–56, 583–601 (1992); C.-S. Kim and H.-I. Yoo, J. Electrochem. Soc., 143 [9], 2863–2870 (1996).
J.H. Becker and H.P.R. Frederikse, J. Appl. Phys., 33[1], 447–453 (1962).
J. Nowotny and M. Rekas, Ceram. International, 20, 225–235 (1994).
E. Duverger, B. Jannot, M. Maglione, and M. Jannin, Solid State Ionics, 73, 139–145 (1994).
M. DiDomenico, Jr. and S.H. Wemple, Phys. Rev., 166[2], 565–576 (1968).
M. Cardona, Phys. Rev., 140[2A], 651–655 (1965).
W.S. Baer, J. Phys. Chem. Solid., 28, 677–687 (1967).
G.V. Lewis and C.R.A. Catlow, J. Phys. Chem. Solids, 47[1], 89–97 (1986).
E.K. Chang, A. Mehta, and D.M. Smyth, pp. 35–45 in Proc. the Symposium on Electro-Ceramics, and Solid State Ionics, H.L. Tuller and D.M. Smyth, eds., (The Electrochem. Soc., Inc., NJ, 1988).
G.H. Jonker, Philips Res. Repts., 23, 131–138 (1968).
C. Wagner, Progr. Solid State Chem., 7, 1–37 (1972).
H. Ihrig, J. Phys. C, 9, 3469–3474 (1976).
H. Ihrig and D. Hennings, Phys. Rev. B, 17[12], 4593–4599 (1978).
J.P. Boyeaux and F.M. Michel-Calendini, J. Phys. C, 12, 545–556 (1979).
E. Iguchi, N. Kuboto, T. Nakamori, N. Yamamoto, and K.J. Lee, Phys. Rev. B, 43[10], 8646–8649 (1991).
J. Nowotny and M. Rekas, Ceram. International, 20, 257-263 (1994).
H. Schmalzried, Progr. Solid State Chem., 2, 265–303 (1965).
N. Nowotny and M. Rekas, Solid State Ionics, 49, 135–154 (1991).
G.V. Lewis and C.R.A. Catlow, Radiat. Eff., 73[1–4], 307–314 (1983).
J.F. Baumard and P. Abelard, Solid State Ionics, 12, 47–51 (1984).
I. Burn, J. Mat. Sci., 14, 2453–58 (1979).
K.H. Härdtl and R. Wernicke, Solid State Comm., 10, 153–157 (1972).
R.M. Waser, J. Am. Ceram. Soc., 72[12], 2234–2240 (1989).
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Song, CR., Yoo, HI. & Kim, JY. Mn-doped BaTiO3: Electrical Transport Properties in Equilibrium State. Journal of Electroceramics 1, 27–39 (1997). https://doi.org/10.1023/A:1009994230779
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DOI: https://doi.org/10.1023/A:1009994230779