Abstract
The preparation and structural characterization of [YbI2(DME)2] are reported. The complex crystallizes in the triclinic space group P 1¯: a = 13.0094 (10), b=14.504(3), c = 14.668 (3) Å, α = 115.281(10) β = 106.74(2), γ = 105.97(2)°. The metal center of the complex exhibits a distorted pentagonal bipyramidal coordination geometry which involves a rare example of a monodentate DME ligand.
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Schaverien, C.J. Adv. Organomet. Chem. 1994, 36, 283.
Molander, G.A. Chem. Rev. 1992, 92, 29.
Eaborn, C.; Hitchcock, P.B.; Izod, K.; Smith, J.D. J. Am. Chem. Soc. 1994, 116, 12071.
Evans, W.J.; Gummersheimer, T.S.; Ziller, J.W. J. Am. Chem. Soc. 1995, 117, 8999, (b) Sen, A.; Chebolu, V.; Rheingold, A.L. Inorg. Chem. 1987, 126, 1821.
van den Hende, J.R.; Hitchcock, P.B.; Holmes, S.A.; Lappert, M.F.; Leung, W.P.; Mak, T.C.W.; Prashar, S. J. Chem. Soc. Dalton Trans. 1995, 1427.
Hakansson, M.; Vestergren, M.; Gustafsson, B.; Hilmersson, G. Angew. Int. Ed. Engl. 1999, 38, 2199 (b) Evand, W.J.; Broomhall-Dillard, R.N.R.; Ziller, J.W. Polyhedron 1998, 17, 3361.
Bochkarev, M.N.; Fedushkin, I.L.; Fagin, A.A.; Petrovskaya, T.V.; Ziller, J.W.; Broomhall-Dillard, R.N.R.; Evans, W.J. Angew. Chem. Int. Ed. Engl. 1997, 36, 133.
Fedushkin, I.L.; Weydert, M.; Fagin, A.A., Nefedov, S.E.; Ermenko, I.L.; Bochkarev, M.N.; Schumann, H. Z. Naturforsch. 1999, 54b, 466.
Duncalf, D.J.; Hitchcock, P.B.; Lawless, G.A. J. Chem. Soc. Chem. Commun. 1996, 269.
Sheldrick, G.M. SHELX-97; University of Göttingen, Germany, 1997.
Walker, N.P.C.; Stuart, D. Acta Crystallogr. 1983, A39, 158.
Shannon, R.D. Acta Crystallogr. 1976, 32, 751.
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Hibbs, D.E., Jones, C. & Richards, A.F. The structural characterization of YbI2(DME)3. Journal of Chemical Crystallography 29, 1107–1110 (1999). https://doi.org/10.1023/A:1009557708382
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DOI: https://doi.org/10.1023/A:1009557708382