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Hexa(1-vinylimidazole)Co(II) perchlorate

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Abstract

A new cobalt(II) complex of 1-vinylimidazole (vinim) has been synthesized as the perchlorate salt and structurally characterized. The molecular structure of the complex exhibits six coordination in which the geomety is a distorted octahedron. The vinylimidazole ring is coordinated through the imidazole nitrogen, as expected from earlier spectroscopic studies of related adducts. The space group is P21/n, with a = 8.512(2), b = 13.857(2), c = 16.146(2) Å, β = 96.30(1)°, V = 989.31 Å3, and Z = 2.

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Authors and Affiliations

  1. Department of Chemistry, Karaelmas University, 67100, Zonguldak, Turkey

    Yakup Baran

  2. Institution of Inorganic Chemistry, Technical Universit of Wien, Wien, Austria

    Wolfgang Linert

Authors
  1. Yakup Baran
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  2. Wolfgang Linert
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Baran, Y., Linert, W. Hexa(1-vinylimidazole)Co(II) perchlorate. Journal of Chemical Crystallography 29, 1077–1079 (1999). https://doi.org/10.1023/A:1009541305656

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  • DOI: https://doi.org/10.1023/A:1009541305656

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