Skip to main content
SpringerLink
Log in

Crystal structure of the molecular inclusion complex of 5, 17-di-t-butyl-26, 28-disubstituted calix[4]arene with acetone (1:3)

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Crystal structure of inclusion complex of 5, 17-di-t-butyl-26, 28-disubstituted calix[4]arene 3 with acetone, [(C54H58N2O6·CH3COCH3)·2CH3COCH3], was determined by X-ray crystallographic analysis. It possesses space group C2/c, with a = 26.277(8), b = 12.967(5), c = 20.355(4) Å, β = 124.845(14)°, and D calc = 1.173 mg/m3 for Z = 4. Crystal data indicate that action of one molecule of compound 3 upon three molecules of acetone forms a clathrate intermolecular inclusion complex.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Vicens, J.; Bhömer, V. Calixarenes—AVersatile Class of Macrocyclic Compounds; Dordrecht: Kluwer, 1991.

    Google Scholar 

  2. Pochini, A.; Ungaro, R. In Comprehensive Supramolecular Chemistry: Calix[4]arenes and Related Hosts; Lehn, J.M.; Vögtle, F., Eds.; Pergamon: New York, 1996; pp 103–142.

    Google Scholar 

  3. Andreetti, G.D.; Ungaro, R.; Pochini, A. J. Chem. Soc. Chem. Commun. 1979, 1005.

  4. Perrin, M.; Gharnati, F.; Oehler, D.; Perrin, R.; Lecocq, S. J. Inclusion Phenom. Mol. Recognit. 1992, 14, 257.

    Google Scholar 

  5. Ungaro, R.; Pochini, A. J. Chem. Soc. Perkin Trans. II 1984, 1979.

  6. Zhang, P-M.; Huang, Z-T. Acta Chim. Sin. 1992, 50, 209.

    Google Scholar 

  7. Brouwer, E.B.; Udachin, K.A.; Enright, G.D.; Ratcliffe, C.I.; Ripmeester, J.A. Chem. Commun. 1998, 5, 587.

    Google Scholar 

  8. Thuery, P.; Keller, N.; Lance, M.; Vigner, J-D.; Nierlich, M. J. Inclusion Phenom. Mol. Recognit. Chem. 1995, 20, 373.

    Google Scholar 

  9. Arduin, A.; McGregor, W.M.; Paganuzzi, D.; Pochini, A.; Secchi, A.; Ugozzoli, F.; Ungaro, R. J. Chem. Soc. Perkin Trans. II 1996, 839.

  10. Brouwer, E.B.; Enright, G.D.; Ripmeester, J.A. Supramol. Chem. 1996, 7, 7.

    Google Scholar 

  11. Bohmer, V.; Ferguson, G.; Frings, M. Acta Crystallogr. Sect. C: Cryst. Struct. Commun. 1997, 53, 1293.

    Google Scholar 

  12. Van Loon, J-D.; Arduin, A.; Coppi, L.; Verboom, W.; Pochini, A.; Ungaro, R.; Harkema, S; Reinhoudt, D.N. J. Org. Chem. 1990, 55, 5639.

    Google Scholar 

  13. XSCANS (version 2.1), Siemens Analytical X-ray Instruments: Madison, WI, 1994.

  14. SHELXTL (version 5.0), Reference Manual, Siemens Industrial Automation, Analytical Instrumentation: Madison, WI, 1995.

  15. Andreetti, G.D.; Ori, F.O.; Ugozzoli, C.; Alfieri, A.; Pochini, A.; Ungaro, R. J. Inclusion Phenom. Mol. Recognit. Chem. 1998, 6, 523.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P. R. China

    Guoyuan Lu, Fang Liu, Yongjiang Liu, Weijiang He, Qian Li & Longgen Zhu

Authors
  1. Guoyuan Lu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Fang Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yongjiang Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Weijiang He
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Qian Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Longgen Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lu, G., Liu, F., Liu, Y. et al. Crystal structure of the molecular inclusion complex of 5, 17-di-t-butyl-26, 28-disubstituted calix[4]arene with acetone (1:3). Journal of Chemical Crystallography 29, 1121–1125 (1999). https://doi.org/10.1023/A:1009514026129

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1009514026129

Search

Navigation