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Composition Dependence of Thermal Expansion and Glass Transition Temperature for Barium Aluminoborate Glasses

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Abstract

The glass transition temperatures and the thermal expansion coefficients below and above the glass transition range are determined for barium aluminoborate glasses over a wide range of compositions containing up to 60 mol % BaO and 35 mol % Al2O3. The behavior of these characteristics is studied depending on the Al2O3 concentration at constant BaO/B2O3 ratios (from 0.2 to 1) and upon replacement of B2O3 by BaO at constant Al2O3 contents (up to 30 mol %). The influence of composition on the properties is interpreted within the concepts of the barium aluminoborate glass structure.

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REFERENCES

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Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, St. Petersburg, 199155, Russia

    V. P. Klyuev & B. Z. Pevzner

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  1. V. P. Klyuev
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  2. B. Z. Pevzner
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Klyuev, V.P., Pevzner, B.Z. Composition Dependence of Thermal Expansion and Glass Transition Temperature for Barium Aluminoborate Glasses. Glass Physics and Chemistry 27, 54–61 (2001). https://doi.org/10.1023/A:1009511904864

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  • DOI: https://doi.org/10.1023/A:1009511904864

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