Abstract
A series of pendant-arm Schiff base macrocycles have been obtained via the cyclocondensation reaction between sodium 2,6-diformyl-4-substitutedphenolates and tris-(2-aminoethyl)- amine derivatives followed by transmetallation with Cu(ClO4)2·6H2O. The resulting dinuclear copper(II) complexes have been characterized by elemental analysis, infrared and mass spectra as well as magnetic moments at room temperature. All complexes have been electrochemically investigated, and two typical compounds have been studied with ESR spectra as well.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
D. Wang, H. Xiong, G. Wang, Z. Han, X. Yang, H. Hu, and K. Yu: J. Chem. Soc. Dalton Trans. 3325 (1994).
G. A. Mclachlan, S. J. Brudenell, G. D. Fallon, R. L. Martin, L. Spiccia, and E. R. T. Tiekink: J. Chem. Soc. Dalton Trans. 439 (1995).
X. H.Bu, D. L. An, Y. T. Chen, M. Shienoya, and E. Kimura: J. Chem. Soc. Dalton Trans. 2289 (1995).
O. Schlager, K. Wieghardt, and B. Nuber: Inorg. Chem. 34, 6449 and 6456 (1995).
A. M. Josceanu, P. Moore, S. C. Rawle, P. Sheldon, and S. M. Smith: Inorg. Chim. Acta 240, 159 (1995).
R. C. Howell, K. V. N. Spence, I. A. Kahwa, A. J. P. White, and D. J. Williams: J. Chem. Soc. Dalton Trans. 961 (1995).
S. Zhu, F. Kou, H. Lin, C. Lin, M. Lin, and Y. Chen: Inorg. Chem. 35, 5851 (1996).
M. D. Vaizra, M. Gurra, F. Mani, and P. Stoppioni: J. Chem. Soc. Dalton Trans. 1173 (1995).
H. Adams, N. A. Bailey, M. J. S. Dwer, D. E. Fenton, P. C. Hellier, P. D. Hempstead, and J-M. Latour: J. Chem. Soc. Dalton Trans. 1207 (1993).
N. A. Bailey, C. O. Rodriguez de Barbarin, D. E. Fenton, P. C. Hellier, P. D. Hempstead, M. Kanesato, and P. B. Leesson: J. Chem. Soc. Dalton Trans. 765 (1995).
S. R. Collinson, and D. E. Fenton: Coord. Chem. Rev. 148, 19 (1996).
H. Adams, N. A. Bailey, S. R. Collinson, D. E. Fenton, C. J. Harding, and S. J. Kitchen: Inorg. Chim. Acta 246, 81 (1996).
M. D. Timken, W. A. Marritt, D. N. Hendrickson, R. A. Gagne, and E. Sinn: Inorg. Chem. 24, 4202 (1985).
M. G. B. Drew, O. W. Howarth, G. G. Morgan, and J. Nelson: J. Chem. Soc. Dalton Trans. 3149 (1994).
P. Chakraborty, and S. K. Chandra: Polyhedron 13, 683 (1994).
M. G. B. Drew, C. J. Harding, V. Mckee, G. G. Morgan, and J. Nelson: J. Chem. Soc. Chem. Commun. 1035 (1994).
F. Arecilla, R. Bastida, A. de Blas, D. E. Fenton, A. Macias, A. Rodriguez, T. Rodriquez-Blas, S. Garcia-Granda, and R. Corzo-Suarez: J. Chem. Soc. Dalton Trans. 409 (1997).
S. Gou, Q. Zeng, X. You, and W. Linert: Proceedings of XXI International Symposium on Macrocyclic Chemisty PB67 (1996).
S. Gou, and D. E. Fenton: Inorg. Chim. Acta 223, 169 (1994).
S. Gou, and Q. Zeng: unpublished work.
K. Zhou, S. Gou, Z. Wang, and Z. Yuan: Polyhedron 14, 3501 (1995).
B. J. Hathaway, and D. E. Billing: Coord. Chem. Rev. 5, 143 (1970).
M. Qian, S. Gou, H.-K. Fun, and X. You: to be submitted.
P. Zanello, S. Tamburini, P. A. Vigato, and G. A. Mazzocchin: Coord. Chem. Rev. 77, 165 (1987).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zeng, Q., Gou, S., Zhu, J. et al. Pendant-Arm Macrocycles Derived from the Cyclocondensation Reaction of Sodium 2,6-Diformyl-4-substitutedphenolates and Tris-(2-aminoethyl)amine Derivatives. Preparation, Characterization and Properties of their Dinuclear Copper(II) Complexes. Journal of Inclusion Phenomena 35, 299–309 (1999). https://doi.org/10.1023/A:1008159301893
Issue Date:
DOI: https://doi.org/10.1023/A:1008159301893