Abstract
The interaction of 11 sulfosuccinic acid ester anionic surfactants with hydroxypropyl-β-cyclodextrin (HPβCD) were determined with reversed-phase thin-layer chromatography and the relative strength of interaction was calculated. The relationship between the strength of interaction and the physicochemical parameters of anionic surfactants was elucidated with principal component analysis (PCA). HPβCD interacted with the anionic surfactants decreasing their hydrophobicity. The distribution of the points of the strength of interaction and physicochemical parameters on the two dimensional nonlinear map of PC loadings suggested that the strength of interaction between the anionic surfactants and HPβCD is of mixed steric character, with hydrophobic and electronic forces being involved in the interaction.
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Cserháti, T., Csiktusnádi kiss, G. & Augustin, J. The Use of Principal Component Analysis for the Study of the Interaction of Anionic Surfactants with Hydroxypropyl-β- Cyclodextrin. Journal of Inclusion Phenomena 33, 123–133 (1999). https://doi.org/10.1023/A:1008044118894
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DOI: https://doi.org/10.1023/A:1008044118894