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Crystal Structure of Nickel- and Cobalt-Diazidotetrapyridinemetal(II)-2(Pyridine) Clathrates

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Abstract

[MPy4(N3)2]⋅2Py (M = Ni, Co) are clathrates where two of six pyridine species are included in the crystal structure of the host complex without chemical bonding. The clathrates are isostructural, orthorhombic, space group Pnna (52), Z = 4. For the Ni compound a = 14.958(5), b = 11.909(5), c = 17.517(7) Ú, V = 3120(2) Ú3, µ = 12.25 cm-1, final R = 0.057.The Cocompound is of very similar structure (a = 14.980(3), b =11.980(2), c = 17.350(5) Ú, V = 3114(1) Ú3, µ = 46.50 cm-1. The metal cation in the host molecule is surrounded by six donor nitrogens of two terminal azido-groups in trans-positions and four pyridine ligands. The complex molecule lies on a twofold axis parallel to a.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch, Lavrentyeva 3, 630090, Novosibirsk, Russia

    D.V. Soldatov

  2. Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44, 01 224, Warszawa, Poland

    J. Lipkowski

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  1. D.V. Soldatov
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  2. J. Lipkowski
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Soldatov, D., Lipkowski, J. Crystal Structure of Nickel- and Cobalt-Diazidotetrapyridinemetal(II)-2(Pyridine) Clathrates. Journal of Inclusion Phenomena 30, 99–109 (1998). https://doi.org/10.1023/A:1007931115010

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