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Contact Angle and Contact Mechanics of a Glass/Epoxy Interface

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Abstract

An attempt was made to extract the thermodynamic work of adhesion from contact angle measurements and contact mechanics in order to compare it with interfacial toughness values of a glass/epoxy interface. The three probe liquid method, in conjunction with laser goniometry, yielded a value of the work of adhesion of 93 mJ/m2. This was an order of magnitude less than the value extracted from the Maugis solution for contacting spheres with surface interactions. These work of adhesion values were both lower than the 1.5 J/m2 which was determined in a parallel study of interfacial fracture as a mode-mix independent component of the overall interfacial toughness. Some of the reasons for these differences are explored.

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References

  • Ahn, D. and Shull, K.R. (1996). JKR studies of acrylic elastomer adhesion to glassy polymer substrates. Macromolecules 29, 4381–4390.

    Article  ADS  Google Scholar 

  • Azimi, H. R., Pearson, R.A. and Lloyd, T.B. (1995). Fundamentals of adhesion: The utility of three-liquid probe method. Applications of Fracture Mechanics in Electronic Packaging and Materials (Edited by T.Y. Wu, et al.), American Society of Mechanical Engineering, EEP-11/MD-64, 155–161.

  • Chaudury, M.K. and Whitesides, G.M. (1991). Direct measurement of interfacial interactions between semispherical lenses and flat sheets of poly(dimethylsiloxane) and their chemical derivatives. Langmuir 7, 1013–1025.

    Article  Google Scholar 

  • Chen, Y.L., Helm, C.A. and Isrealachvili, J.N. (1991). Molecular mechanisms associated with adhesion and contact angle hysteresis. Journal of Physical Chemistry 95, 10736–10747.

    Article  Google Scholar 

  • Comninou, M. and Schmueser, D. (1979). The interface crack in a combined tension-compression and shear field. Journal of Applied Mechanics 46, 345–348.

    MATH  Google Scholar 

  • Derjaguin, R.V., Muller, V.M. and Toporov, Y.P. (1975). Effect of contact deformations on the adhesion of particles. Journal of Colloid and Interface Science 53, 314–326.

    Article  Google Scholar 

  • Derjaguin, B.V., Krotova, N.A. and Toporov, Y.P. (1982). Emission of high-speed electrons and other phenomena accompanying the process of breaking adhesion bonds. Microscopic Aspects of Adhesion and Lubrication (Edited by J.M. Georges), Elsevier Scientific, New York, 471–487.

    Google Scholar 

  • Falsafi, A., Deprez, P., Bates, F.S. and Tirrell, M. (1996). Direct measurement of adhesion between viscoelastic solid polymers. Proceedings of the 19th Annual Meeting of the Adhesion Society (Edited by Thomas C. Ward), 49–52.

  • Good, R., Chaudhury, M.K. and van Oss, C.J. (1991). Theory of adhesive forces across interfaces 2. Interfacial hydrogen bonds as acid-base phenomena and as factors enhancing adhesion. Fundamentals of Adhesion (Edited by L.-H. Lee), Plenum Press, New York, 153–172.

    Google Scholar 

  • Horn, R.G. and Smith, D.T. (1992). Contact electrification and adhesion between dissimilar materials. Science 256, 362–364.

    ADS  Google Scholar 

  • Israel, S.C., Yang, W.C., Chae, C.H. and Wong, C. (1989). Characterization of polymer surfaces by laser contact angle goniometry. Polymer Preprints, Division of Polymer Chemistry 30, 328–329.

    Google Scholar 

  • Israelachvili, J.N., Fischer, L.R., Horn, R.G. and Christenson, H.K. (1982). Measurement of adhesion between short-range forces and molecularly smooth surfaces in undersaturated vapours and in organic liquids. Microscopic Aspects of Adhesion and Lubrication (Edited by J.M. Georges), Elsevier Scientific, New York, 55–69.

    Google Scholar 

  • Johnson, K.L., Kendall, K. and Roberts, A.D. (1971). Surface energy and the contact of elastic solids. Proceedings of the Royal Society of London A 324, 301–313.

    Article  ADS  Google Scholar 

  • Kinloch, A.J. (1987). Chapter 3 in Adhesion and Adhesives, Chapman Hall, London.

    Google Scholar 

  • Kinloch, A.J., Dukes, W.A. and Gledhill, R.A. (1975). Durability of joints. Adhesion Science and Technology 2, 597–614.

    Google Scholar 

  • Liang, Y.-M. and Liechti, K.M. (1995). Toughening mechanisms in mixed-mode interfacial fracture. International Journal of Solids and Structures 32, 957–958.

    Article  Google Scholar 

  • Liang, Y.-M. and Liechti, K.M. (1996). On the large deformation and localization behavior of an epoxy resin under multiaxial stress states. International Journal of Solids and Structures 32, 1479–1500.

    Article  Google Scholar 

  • Liechti, K.M. and Hanson, E.C. (1988). Nonlinear effects in mixed-mode delaminations. International Journal of Fracture 36, 199–217.

    Google Scholar 

  • Liechti, K.M. and Chai, Y.-S. (1992). Asymmetric shielding in interfacial fracture under in-plane shear. Journal of Applied Mechanics 59, 295–304.

    Google Scholar 

  • Liechti, K.M. and Liang, Y.M. (1992). The interfacial fracture characteristics of bimaterial and sandwich blister specimens. International Journal of Fracture 55, 95–114.

    Article  ADS  Google Scholar 

  • Mangipudi, V.S., Tirrell, M. and Pocius, A.V. (1996). Comparison of polymer surface energies measured by contact mechanics and contact angles. Proceedings of the 19th Annual Meeting of the Adhesion Society (Edited by Thomas C. Ward), 7–9.

  • Maugis, D. (1992). Adhesion of spheres: The JKR — DMT transition using a Dugdale model. Journal of Colloid and Interface Science 150, 243–269.

    Article  Google Scholar 

  • Maugis, D. and Gauthier-Manuel, B. (1995). JKR — DMT transition in the presence of a liquid meniscus. Fundamentals of Adhesion and Interfaces (Edited by D.S. Rimai, L.P. DeMejo and K.L. Mittal), VSP, 49–60.

  • Merrill, W.W., Pocius, A.V., Thakker, B.V. and Tirrell, M. (1991). Direct measurement of molecular level adhesion forces between biaxially oriented solid polymer films. Langmuir 7 1013–1025.

    Article  Google Scholar 

  • Muller, V.M. Yushchenko, V.S. and Derjaguin, B.V. (1980). On the influence of molecular forces on the deformation of an elastic sphere and it's sticking to a rigid plane. Journal of Colloid and Interface Science 77, 91–101.

    Article  Google Scholar 

  • Rodin, G.J. (1996). Squeeze film between two spheres in a power-law fluid. Journal of Non-Newtonian Fluid Mechanics 63, 141–152.

    Article  Google Scholar 

  • Schnapp, S.T. (1996). The influence of surface interactions on interfacial contact. Engineering Mechanics Research Laboratory Report # EMRL 96-4. The University of Texas at Austin.

  • Swadener, J.G. and Liechti, K.M. (1996). Asymmetric shielding mechanisms in the mixed-mode fracture of a glass/epoxy interface. Engineering Mechanics Research Laboratory Report # EMRL 96-14. The University of Texas at Austin.

  • Tvergaard, V. and Hutchinson, J.W. (1992). The relation between crack growth resistance and fracture process parameters in elastic-plastic solids. Journal of the Mechanics and Physics of Solids 40, 1377–1397.

    Article  MATH  ADS  Google Scholar 

  • Tvergaard, V, and Hutchinson, J.W. (1993). The influence of plasticity on mixed mode interface toughness. Journal of the Mechanics and Physics of Solids 41, 1119–1135.

    Article  MATH  ADS  Google Scholar 

  • Tvergaard, V. and Hutchinson, J.W. (1994). Toughness of an interface along a thin ductile layer joining elastic solids. Philosophical Magazine A 70, 641–656.

    ADS  Google Scholar 

  • Ungsuwarungsri, T. and Knauss, W.G. (1987). The role of damage-softened material in the fracture of composites and adhesives. International Journal of Fracture 35, 221–241.

    Article  Google Scholar 

  • Ungsuwarungsri, T. and Knauss, W.G. (1988). A nonlinear analysis of an equilibrium craze: Part I — Problem formulation and solution. Journal of Applied Mechanics 55, 44–51.

    Article  Google Scholar 

  • Ungsuwarungsri, T. and Knauss, W.G. (1988). A nonlinear analysis of an equilibrium craze: Part II — Simulations of craze and crack growth. Journal of Applied Mechanics 55, 52–58.

    Google Scholar 

  • Zimmerman, K.A., Langford, S.C. and Dickinson, J.T. (1991). Electrical transients during interfacial debonding and pull-out of a metal rod from an epoxy matrix. Journal of Applied Physics 70, 4808–4815.

    Article  ADS  Google Scholar 

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Liechti, K., Schnapp, S. & Swadener, J. Contact Angle and Contact Mechanics of a Glass/Epoxy Interface. International Journal of Fracture 86, 361–374 (1997). https://doi.org/10.1023/A:1007472628431

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