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Structural Interpretation of the Concentration Dependences of Molar Volume in Lead Silicate Glasses

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Abstract

It is found that the type of the concentration dependence of molar volume in binary lead silicate glasses containing modifier oxides of groups I and II of the periodic system is determined by the degree of depolymerization of the structural lattice. The molar volume of the structural lattice of the considered glasses is additive and determined by the partial values of the molar volumes of their “siliceous” and “plumbate” components.

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REFERENCES

  1. A. I. Rabukhin, “Structural interpretation of concentration dependences of molar volume of glasses in R2O - SiO2 and RO - SiO2 systems,” Steklo Keram., No. 11, 6–9 (1999).

    Google Scholar 

  2. A. I. Rabukhin, “Structural interpretation of concentration dependences of the molar volume of glasses in R2O - ′R2O - SiO2,RO - RO - SiO2, and R2O - RO - SiO2 systems,” Steklo Keram., No. 12, 13–16 (1999).

    Google Scholar 

  3. O. V. Mazurin, M. V. Strel'tsina, and T. P. Shvaiko-Shvaikovskaya, Properties of Glasses and Glass-Forming Melts, A Reference Book, Vol. 1 [in Russian], Nauka, Leningrad (1973).

    Google Scholar 

  4. M. Leventhal and P. J. Bray, “Nuclear magnetic resonance investigation of compounds and glasses in the systems PbO - B2O3 and PbO - SiO2,” Phys. Chem. Glass., 6(4), 113–125 (1965).

    Google Scholar 

  5. M. F. Mydler and N. J. Kreidl, “X-ray diffraction study of lead silicate glasses,” Phys. Chem. Glass., 11(6), 196–204 (1970).

    Google Scholar 

  6. J. Gotz, D. Hobbel, and W. Wiker, “On constitution of binary silicate glasses,” J. Non-Cryst. Solids, 22(3), 391–398 (1976).

    Google Scholar 

  7. M. J. Smets and T. P. A. Lomen, “The structure of glasses and crystalline compounds in system PbO - SiO2 studied by photoelectron spectroscopy,” J. Non-Cryst. Solids, 48(4), 423–430 (1982).

    Google Scholar 

  8. M. Imaoka, H. Hosegava, and I. Yasui, “X-ray diffraction analysis of the structure of glasses in system PbO - SiO2,” J. Non-Cryst. Solids, 85(3), 393–401 (1986).

    Google Scholar 

  9. A. L. Shakhmin and A. M. Tyutikov, “Study of the electronic structure of lead silicate glasses by x-ray photoelectron spectroscopy,” Fiz. Khim. Stekla, 16(6), 833–839 (1990).

    Google Scholar 

  10. N. A. Toropov, V. P. Barzakovskii, V. V. Lapin, et al., Phase Diagrams of Silicate Systems, A Reference Book, Vol. 1, Binary Systems [in Russian], Nauka, Leningrad (1969).

    Google Scholar 

  11. T. Penkalya, Essays in Crystal Chemistry [in Russian], Khimiya, Leningrad (1974).

  12. A. N. Vinchell and G. V. Vinchell, Optical Properties of Synthesized Minerals [in Russian], Mir, Moscow (1967).

    Google Scholar 

  13. I. Naray-Szabo, “Zusammenhang zwischhen der struktur und den physikalischen eigenschaften der glases,” Acta Phys. Acad. Scientiarum Hungaricae, 8(1 - 2), 37–64 (1957).

    Google Scholar 

  14. O. V. Mazurin, M. V. Strel'tsina, and T. P. Shvaiko-Shvaikovskaya, Properties of Glasses and Glass-Forming Melts, A Reference Book, Vol. 3, Part 1 [in Russian], Nauka, Leningrad (1977).

    Google Scholar 

  15. O. V. Mazurin, M. V. Strel'tsina, and T. P. Shvaiko-Shvaikovskaya, Properties of Glasses and Glass-Forming Melts, A Reference Book, Vol. 4, Part 2 [in Russian], Nauka, Leningrad (1981).

    Google Scholar 

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Rabukhin, A.I. Structural Interpretation of the Concentration Dependences of Molar Volume in Lead Silicate Glasses. Glass and Ceramics 57, 338–341 (2000). https://doi.org/10.1023/A:1007190320156

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