Abstract
It is found that the type of the concentration dependence of molar volume in binary lead silicate glasses containing modifier oxides of groups I and II of the periodic system is determined by the degree of depolymerization of the structural lattice. The molar volume of the structural lattice of the considered glasses is additive and determined by the partial values of the molar volumes of their “siliceous” and “plumbate” components.
Similar content being viewed by others
REFERENCES
A. I. Rabukhin, “Structural interpretation of concentration dependences of molar volume of glasses in R2O - SiO2 and RO - SiO2 systems,” Steklo Keram., No. 11, 6–9 (1999).
A. I. Rabukhin, “Structural interpretation of concentration dependences of the molar volume of glasses in R2O - ′R2O - SiO2,RO - RO - SiO2, and R2O - RO - SiO2 systems,” Steklo Keram., No. 12, 13–16 (1999).
O. V. Mazurin, M. V. Strel'tsina, and T. P. Shvaiko-Shvaikovskaya, Properties of Glasses and Glass-Forming Melts, A Reference Book, Vol. 1 [in Russian], Nauka, Leningrad (1973).
M. Leventhal and P. J. Bray, “Nuclear magnetic resonance investigation of compounds and glasses in the systems PbO - B2O3 and PbO - SiO2,” Phys. Chem. Glass., 6(4), 113–125 (1965).
M. F. Mydler and N. J. Kreidl, “X-ray diffraction study of lead silicate glasses,” Phys. Chem. Glass., 11(6), 196–204 (1970).
J. Gotz, D. Hobbel, and W. Wiker, “On constitution of binary silicate glasses,” J. Non-Cryst. Solids, 22(3), 391–398 (1976).
M. J. Smets and T. P. A. Lomen, “The structure of glasses and crystalline compounds in system PbO - SiO2 studied by photoelectron spectroscopy,” J. Non-Cryst. Solids, 48(4), 423–430 (1982).
M. Imaoka, H. Hosegava, and I. Yasui, “X-ray diffraction analysis of the structure of glasses in system PbO - SiO2,” J. Non-Cryst. Solids, 85(3), 393–401 (1986).
A. L. Shakhmin and A. M. Tyutikov, “Study of the electronic structure of lead silicate glasses by x-ray photoelectron spectroscopy,” Fiz. Khim. Stekla, 16(6), 833–839 (1990).
N. A. Toropov, V. P. Barzakovskii, V. V. Lapin, et al., Phase Diagrams of Silicate Systems, A Reference Book, Vol. 1, Binary Systems [in Russian], Nauka, Leningrad (1969).
T. Penkalya, Essays in Crystal Chemistry [in Russian], Khimiya, Leningrad (1974).
A. N. Vinchell and G. V. Vinchell, Optical Properties of Synthesized Minerals [in Russian], Mir, Moscow (1967).
I. Naray-Szabo, “Zusammenhang zwischhen der struktur und den physikalischen eigenschaften der glases,” Acta Phys. Acad. Scientiarum Hungaricae, 8(1 - 2), 37–64 (1957).
O. V. Mazurin, M. V. Strel'tsina, and T. P. Shvaiko-Shvaikovskaya, Properties of Glasses and Glass-Forming Melts, A Reference Book, Vol. 3, Part 1 [in Russian], Nauka, Leningrad (1977).
O. V. Mazurin, M. V. Strel'tsina, and T. P. Shvaiko-Shvaikovskaya, Properties of Glasses and Glass-Forming Melts, A Reference Book, Vol. 4, Part 2 [in Russian], Nauka, Leningrad (1981).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rabukhin, A.I. Structural Interpretation of the Concentration Dependences of Molar Volume in Lead Silicate Glasses. Glass and Ceramics 57, 338–341 (2000). https://doi.org/10.1023/A:1007190320156
Issue Date:
DOI: https://doi.org/10.1023/A:1007190320156