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Reactions of 2,2′-bipyridine (bpy) and 1,10-phenanthroline (phen) with yttrium(III) nitrate: preparation, X-ray crystal structures and spectroscopic characterization of the bis-bpy and bis-phen complexes

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Abstract

Y(NO3)3 · 5H2O reacts with 2,2′-bipyridine (bpy) and 1,10-phenanthroline (phen) to yield similar complexes of 1:2 yttrium:ligand stoichiometry. The crystal structures of the two complexes, namely, [Y(NO3)3(bpy)2] (1) and [Y(NO3)3(phen)2] (2), are reported. The three nitrate groups are O,O′-bidentate and the organic ligands are also bidentate. In both structures the metal ion lies on a crystallographic two-fold axis. The stereochemistry about YIII can be viewed as a sphenocorona. The new complexes were characterized by elemental analyses and spectroscopic (i.r., 1H-n.m.r. and 13C-n.m.r.) techniques. The data are discussed in terms of the nature of bonding and known solid state structures.

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Authors and Affiliations

  1. Department of Chemistry, University of Patras, 265 00, Patras, Greece

    Athanassios K. Boudalis, Vassilios Nastopoulos & Spyros P. Perlepes

  2. Institute of Materials Science, NCSR 'Demokritos', 153 10, Aghia Paraskevi Attikis, Greece

    Catherine P. Raptopoulou & Aris Terzis

Authors
  1. Athanassios K. Boudalis
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  2. Vassilios Nastopoulos
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  3. Spyros P. Perlepes
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  4. Catherine P. Raptopoulou
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  5. Aris Terzis
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Boudalis, A.K., Nastopoulos, V., Perlepes, S.P. et al. Reactions of 2,2′-bipyridine (bpy) and 1,10-phenanthroline (phen) with yttrium(III) nitrate: preparation, X-ray crystal structures and spectroscopic characterization of the bis-bpy and bis-phen complexes. Transition Metal Chemistry 26, 276–281 (2001). https://doi.org/10.1023/A:1007185119324

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