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Mixed ligand complexes involving aminoacid dithiocarbamates, substituted phosphines and nickel(II)

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Abstract

Mixed ligand complexes involving four aminoacid dithiocarbamates (RR′dtc = glydtc− (R = H; R′ = H), methdtc− (R = H; R′ = C3H7S), sardtc− (R = Me; R′ = H), trydtc− (R = H; R′ = C9H8N), substituted phosphines [PPh3, Ph2PCH2CH2PPh2(dppe)] and nickel(II) are reported. All are diamagnetic. Thermal analyses of the complexes are in keeping with the proposed formulae. Thermal decomposition of the dithiocarbamate moiety proceeds through the formation of Ni(SCN)2. PPh3 and dppe are lost in the initial decomposition stages.

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Authors and Affiliations

  1. Department of Chemistry, Annamalai University, Annamalainagar, 608 002, India

    Subbiah Thirumaran & Kuppukkannu Ramalingam

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  1. Subbiah Thirumaran
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  2. Kuppukkannu Ramalingam
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Thirumaran, S., Ramalingam, K. Mixed ligand complexes involving aminoacid dithiocarbamates, substituted phosphines and nickel(II). Transition Metal Chemistry 25, 60–62 (2000). https://doi.org/10.1023/A:1007097629965

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