Skip to main content
SpringerLink
Log in

Copper(II)–1,2-bis(thiocarbamoyl)hydrazine and copper(II)–(1-carbamoyl-2-thiocarbamoyl)hydrazine complexing in copper(II)hexacyanoferrate(II) gelatin-immobilized matrix systems

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

The complex formation that occurs in gelatin-immobilized copper(II)hexacyanoferrate(II) matrices upon contact with aqueous alkaline (pH 12.0) solutions of 1,2-bis(thiocarbamoyl)hydrazine, H2NC(S)NHNHC(S)NH2 and 1-carbamoyl-2-(thiocarbamoyl)hydrazine, H2NC(O)NHNHC(S)NH2 has been studied. The reaction of each of these ligands with copper(II) is preceded by the destruction of copper(II)hexacyanoferrate(II) in an alkaline medium to form a polymeric copper(II) hydroxide, which is involved in the subsequent copper(II)–ligand complex formation. In both CuII–N ligand systems, two complex compounds are formed; the water-insoluble Cu2B2(H2O)2 dimer and a water-soluble product of tentative composition [CuB(HB)]− (H2B = ligand).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N.K. Dutt, Z Anal. Chem., 177, 7 (1960).

    Google Scholar 

  2. N.K. Dutt, J. Indian Chem. Soc., 44, 98 (1967).

    Google Scholar 

  3. N.K. Dutt, Z Anal. Chem., 183, 376 (1961).

    Google Scholar 

  4. P.K. De, Indian Appl. Chem., 30, 173 (1967).

    Google Scholar 

  5. E. Jacobsen and C. Hansteen, Anal. Chim. Acta, 28, 249 (1963).

    Google Scholar 

  6. A. Dutta Ahmed and P.K. Mandal, J. Inorg. Nucl. Chem., 28, 1633 (1966).

    Google Scholar 

  7. O.V. Mikhailov, Transition Met. Chem., 22, 535 (1997).

    Google Scholar 

  8. O.V. Mikhailov, T.B. Tatarintseva and V.K. Polovnyak, J. Imaging Sci. Technol., 38, 343 (1994).

    Google Scholar 

  9. O.V. Mikhailov and M.A. Kazymova, Transition Met. Chem., 23, 195 (1998).

    Google Scholar 

  10. P.A.S. Smith, Organic Reactions, R. Adams (Ed.), New York, 1947, vol. 3.

  11. O.V. Mikhailov, Russ. J. Coord. Chem., 18, 1008(1992).

    Google Scholar 

  12. O.V. Mikhailov, Indian J. Chem., 30A, 252 (1991).

    Google Scholar 

  13. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th Edit., Wiley, New York, 1991.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Analytical Chemistry, Kazan State Technological University, K. Marx Street 68, 420015, Kazan, Russia

    Oleg V. Mikhailov, Tatyana B. Tatarintseva & Vladimir F. Sopin

Authors
  1. Oleg V. Mikhailov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Tatyana B. Tatarintseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Vladimir F. Sopin
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mikhailov, O.V., Tatarintseva, T.B. & Sopin, V.F. Copper(II)–1,2-bis(thiocarbamoyl)hydrazine and copper(II)–(1-carbamoyl-2-thiocarbamoyl)hydrazine complexing in copper(II)hexacyanoferrate(II) gelatin-immobilized matrix systems. Transition Metal Chemistry 25, 32–36 (2000). https://doi.org/10.1023/A:1007088306282

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1007088306282

Keywords

Search

Navigation