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Copper(II)–8-mercaptoquinoline, copper(II)–5,8-dimercaptoquinoline and copper(II)–5-thiomethyl-8-mercaptoquinoline complexing in a copper(II)hexacyanoferrate(II) gelatin-immobilized matrix

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Abstract

Novel complexing processes in the CuII–8-mercaptoquinoline, CuII–5,8-dimercaptoquinoline and CuII–5-thiomethyl-8-mercaptoquinoline systems proceeding in the copper(II)hexacyanoferrate(II) gelatin-immobilized matrix in contact with aqueous solutions of the ligands indicated, have been studied. Under the conditions specified for complexing in the CuII–8-mercaptoquinoline system, only a monomeric water-insoluble coordination compound was formed. In the CuII–5,8-dimercaptoquinoline system, three coordination compounds were formed and, in the CuII–5-thiomethyl-8-mercaptoquinoline system, two such compounds were formed. Conversely, complexing in solution or solid phase results in the formation only coordination compounds in each of the system studied.

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Authors and Affiliations

  1. Kazan State Technological University, K. Marx, Street 68, 420015, Kazan, Russia

    Oleg V. Mikhailov, Tatyana B. Tatarintseva, Tatyana S. Gorbunova & Vladimir F. Sopin

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  1. Oleg V. Mikhailov
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  2. Tatyana B. Tatarintseva
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  3. Tatyana S. Gorbunova
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  4. Vladimir F. Sopin
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Mikhailov, O.V., Tatarintseva, T.B., Gorbunova, T.S. et al. Copper(II)–8-mercaptoquinoline, copper(II)–5,8-dimercaptoquinoline and copper(II)–5-thiomethyl-8-mercaptoquinoline complexing in a copper(II)hexacyanoferrate(II) gelatin-immobilized matrix. Transition Metal Chemistry 25, 45–51 (2000). https://doi.org/10.1023/A:1007077018327

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