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Synthesis and structural characterization of copper(II) complex of 2,2′-bipyridyl and L-lysine

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Abstract

The mixed ligand copper(II) complex of 2,2′-bipyridyl and L-lysine was synthesized from 2,2′-bipyrdine, lysine monohydrochloride and copper perchlorate. The resultant complex was characterized by elemental analysis, X-ray crystallography, IR and thermogravimetric analysis. X-ray studies showed that the title complex is a dimer. The geometry around copper atom is distorted square planar in which the Cu atom is bonded with N and O atoms from L-lysine and N, N atoms of 2,2′-bipyridyl ligand. The crystal structure is orthorhombic with unit cell parameters a = 10.5330(9) Å, b = 13.2169(12) Å, c = 32.618(3) Å; V = 4540.9(7) Å, D x = 8, 1.705 Mg/m3, Mr = 582.83. IR spectral band has been studied and are agreed well with those obtained from the values of the expected CHN analyses and X-ray diffraction. Thermal decomposition of the complex has also been studied under an inert atmosphere.

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Authors and Affiliations

  1. School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK

    K. H. Thebo & J. Raftery

  2. Centres of Excellence in Science & Applied Technologies (CESAT), Islamabad, Pakistan

    K. H. Thebo

  3. Department of Chemistry, University of Sargodha, Sargodha, Pakistan

    H. A. Shad

  4. Department of Chemistry, Shah Abdul Latif University Khair Pur Mir, 66020, Sindh, Pakistan

    A. A. Thebo

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  1. K. H. Thebo
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  2. H. A. Shad
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  3. A. A. Thebo
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  4. J. Raftery
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Correspondence to K. H. Thebo.

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Thebo, K.H., Shad, H.A., Thebo, A.A. et al. Synthesis and structural characterization of copper(II) complex of 2,2′-bipyridyl and L-lysine. Crystallogr. Rep. 59, 1063–1067 (2014). https://doi.org/10.1134/S1063774514080082

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  • DOI: https://doi.org/10.1134/S1063774514080082

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