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Correlation between i.r. spectra and thermal decomposition of cobalt(II), nickel(II), copper(II) and mercury(II) complexes with piperidinedithiocarbamate and pyrrolidinedithiocarbamate

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Abstract

The thermal decomposition of pyrrolidinedithiocarbamate and piperidinedithiocarbamate complexes of CoII, NiII, CuII and HgII have been studied by thermogravimetry and differential scanning calorimetry. The decomposition intermediates and final products were identified by their X-ray diffraction patterns. The i.r. spectra are discussed in terms of the thermal decomposition pathways.

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References

  1. A.K. Sharma, Thermochim. Acta, 104, 339 (1986).

    Google Scholar 

  2. R.J. Magee and J.O. Hill, Rev. Anal. Chem., 8, 5 (1985).

    Google Scholar 

  3. S.K. Sengupta and S. Kumar, Termochim. Acta, 72, 349 (1984).

    Google Scholar 

  4. H. Malissa and S. Gomišcek, Anal. Chim. Acta, 27, 402 (1962).

    Google Scholar 

  5. R. Kellner, Mikrochim. Acta, 2, 24 (1975).

    Google Scholar 

  6. R. Kellner, P. Prokopowisk and H. Malissa, Anal. Chim. Acta, 68, 401 (1974).

    Google Scholar 

  7. W. Sztark, H. Malissa and R. Kellner, Anal. Chim. Acta, 63, 285 (1973).

    Google Scholar 

  8. H.O. Desseyn, A.C. Fabretti, F. Forghieri and C. Preti, Spectrochim. Acta, 41A, 1105 (1985).

    Google Scholar 

  9. R. Kellner, Anal. Chim. Acta, 63, 277 (1973).

    Google Scholar 

  10. K.S. Siddiq, M.A.A. Shah and S.A.A. Zaidi, Bull. Chem. Soc. Fr., 49 (1983).

  11. R. Payne, R.J. Magee and J. Liesegang, Chem. Phys. Lett., 93, 103 (1982).

    Google Scholar 

  12. S. Gomišcek, L. Golic and Z. Lengar, Anal. Chim. Acta, 79, 296 (1975).

    Google Scholar 

  13. S. Gomišcek, Z. Lengar, J. Cernetic and V. Hudnik, Anal. Chim. Acta, 73, 97 (1974).

    Google Scholar 

  14. A.C. Fabretti, F. Forghieri, A. Giusti, C. Preti and G. Tosi, Spectrochim. Acta, 40A, 343 (1984).

    Google Scholar 

  15. R.C. West (ed), Handbook of Chemistry and Physics, CRC Press, 1st Student Edit., New York, 1991.

    Google Scholar 

  16. E.T.G. Cavalheiro, M. Ionashiro, G. Marino, S.T. Breviglieri and G.O. Chierice, J. Braz. Chem. Soc., 10, 65 (1999).

    Google Scholar 

  17. Complexometric assay methods with Titriplex®, E. Merck, Darmstadt, 1982.

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Authors and Affiliations

  1. Depto. Química, UFSCar, São Carlos, São Paulo, CP 676, CEP 13565-905, Brazil

    Éder T. G. Cavalheiro

  2. Instituto de Química, UNESP, Araraquara, São Paulo, CP 355, CEP 14800-900, Brazil

    Massao Ionashiro

  3. Inst. de Química de S. Carlos, USP, São Carlos, São Paulo, CP 780, CEP 13560-970, Brazil

    Glimaldo Marino, Susete T. Breviglieri & Gilberto O. Chierice

Authors
  1. Éder T. G. Cavalheiro
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  2. Massao Ionashiro
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  3. Glimaldo Marino
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  4. Susete T. Breviglieri
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  5. Gilberto O. Chierice
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Cavalheiro, É.T.G., Ionashiro, M., Marino, G. et al. Correlation between i.r. spectra and thermal decomposition of cobalt(II), nickel(II), copper(II) and mercury(II) complexes with piperidinedithiocarbamate and pyrrolidinedithiocarbamate. Transition Metal Chemistry 25, 69–72 (2000). https://doi.org/10.1023/A:1007044130951

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