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Synthesis, crystal structure and properties of a manganese(III) Schiff-base complex: [{Mn(vanen)(Him)(H2O)}{Mn(vanen)(Him)2}](ClO4)2 · 4H2O(H2vanen = N,N′-bis(methoxysalicylidene)-1,2-diaminoethane)

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Abstract

A novel manganese(III) complex, [{Mn(vanen)(Him)(H2O)}(Mn(vanen)(Him)}](ClO4)2 · 4H2O [H2vanen = N,N′-bis(methoxysalicylidene)-1,2-diaminoethane], has been synthesized and characterized by elemental analysis, i.r. spectroscopy, t.g.a. and by an X-ray single crystal study. The complex consists of two sets of cations: [Mn(vanen)(Him)(H2O)]+ (A) and [Mn(vanen)(Him)2]+ (B), each of which has six-coordinate geometry, significantly elongated due to the Jahn-Teller distortion at the d4 manganese(III) center. The presence of lattice and coordinate water molecules are also confirmed by the t.g. study and the i.r. spectra.

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Authors and Affiliations

  1. Department of Chemistry, Shanghai Jiaotong University, Shanghai, 200240, P.R. China

    Cun-Gen Zhang, Dan Wu & Cheng-Xue Zhao

  2. Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai, 200232, P.R. China

    Jie Sun & Xiang-Fu Kong

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  1. Cun-Gen Zhang
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  2. Dan Wu
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  3. Cheng-Xue Zhao
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  4. Jie Sun
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  5. Xiang-Fu Kong
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Zhang, CG., Wu, D., Zhao, CX. et al. Synthesis, crystal structure and properties of a manganese(III) Schiff-base complex: [{Mn(vanen)(Him)(H2O)}{Mn(vanen)(Him)2}](ClO4)2 · 4H2O(H2vanen = N,N′-bis(methoxysalicylidene)-1,2-diaminoethane). Transition Metal Chemistry 24, 718–721 (1999). https://doi.org/10.1023/A:1007033830388

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