Abstract
Treatment of [PtCl2(Ptolyl3)2] (tolyl = 4-MeC6H4) with Na2S in benzene gave [Pt2(μ2-S)2(Ptolyl3)4] (1), which is soluble in common organic solvents. Reactions of (1) with various metal complexes have been studied and several polynuclear metal aggregates isolated. These new complexes were characterized by elemental analysis and n.m.r. spectroscopy.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
S. Narayan, V.K. Jain and R.J. Butcher, Polyhedron, 17, 2037 (1998).
D. Fenske, H. Fleischer, H. Krautscheid and J. Magull, Z. Naturforsch., 45B, 127 (1990).
R. Ugo, G.L. Monica, S. Cenini, A. Segre and F. Conti, J. Chem. Soc. A, 522 (1971).
Von M. Schmidt and G.G. Hoffmann, Z. Anorg. Allg. Chem., 464, 209 (1980).
V.W.W. Yam, P.K.Y. Yeung and K.K. Cheung, J. Chem. Soc. Commun., 267 (1995).
M. Capdevila, Y. Carrasco, W. Clegg, R.A. Coxall, P.G. Duarte, A. Lledos, J. Sola and G. Ujaque, Chem. Commun., 597 (1998).
W. Oberhauser, C. Bachmann, T. Stampfl, R. Haid, C. Langes, A. Rieder and P. Bruggeller, Inorg. Chim. Acta, 274, 143 (1998).
C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Chem. Soc., Chem. Commun., 1118 (1983).
C.E. Briant, D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., 851 (1985).
D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., 335 (1987).
B.H. Aw, K.K. Looh, H.S.O. Chan, K.L. Tan and T.S.A. Hor, J. Chem. Soc., Dalton Trans., 3177 (1994).
W. Bos, J.J. Bour, P.P.J. Schlebos, P. Hageman, W.P. Bosman, J.M.M. Smits, J.A.C. van Wietmarschen and P.T. Beurskens, Inorg. Chim. Acta, 119, 141 (1986).
M. Zhou, Y. Xu, C.F. Lam, L.L. Koh, K.F. Mok, P.H. Leung and T.S.A. Hor, Inorg. Chem., 32, 4660 (1993).
M. Zhou, Y. Xu, L.L. Koh, K.F. Mok, P.H. Leung and T.S.A. Hor, Inorg. Chem., 32, 1875 (1993).
H. Liu, A.L. Tan, K.F. Mok and T.S.A. Hor, J. Chem. Soc., Dalton Trans., 4023 (1996).
H. Liu, A.L. Tan, C.R. Cheng, K.F. Mok and T.S.A. Hor, Inorg. Chem., 36, 2916 (1997); C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Organometal Chem., C15, 256 (1983).
C.E. Briant, C.J.B. Gardner, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., 2645 (1984).
F.R. Hartley, The Chemistry of Platinum and Palladium, Wiley, New York, 1973.
J. Chatt and L.M. Venanzi, J. Chem. Soc., 4735 (1957).
J.A. McCleverty and G. Wilkinson, Inorg. Synth., 8, 211 (1966).
V.K. Jain, S. Kannan, R.J. Butcher and J.P. Jasinki, J. Chem. Soc., Dalton Trans., 1509 (1993).
A. Singhal, V.K. Jain, B. Varghese and E.R.T. Tiekink, Inorg. Chim. Acta, 285, 190 (1999).
H.C. Clark, V.K. Jain and G.S. Rao, J. Organometal Chem., 279, 181 (1985).