Abstract
A new five-coordinate nickel(II) complex of a trans[14]diene macrocyclic ligand has been prepared and characterized by X-ray crystallography, u.v. and i.r. spectroscopy. The coordination environment of the nickel(II) ion is a distorted square pyramid with the nickel(II) ion deviating from the level plane 0.25 Å and the SCN ligand at the apical side.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
K.K. Nanda, R. Das, L.K. Thompson, K. Venkatsubramanian and Nag K, Inorg. Chem., 33, 1177 (1994).
E. Huyett, M. Carepo, A. Pamplona, R. Franco, I. Moura, J.J.G. Moura and B.M. Ho€man, J. Am. Chem. Soc., 119, 9291 (1997).
E.P. Day, J. Peterson, M.S. Sendova, M.J. Todd and R.P. Hausinger, Inorg. Chem., 32, 634 (1993).
P.A. Clark and D.E. Wilcox, Inorg. Chem., 28, 1326 (1989).
D.L. Tennent and D.R. McMillin, J. Am. Chem. Soc., 101, 2307 (1979).
H.R. Engeseth, D.R. McMillin and E.L. Ulrich, Inorg. Chim. Acta., 67, 145 (1982).
R.J. Haines and A. McAuley, Coord. Chem. Rev., 39, 71 (1981).
A.B.P. Lever, Inorganic Electronic Spectroscopy (2nd ed.). Elsevier Science Publishing Company Inc., New York, 1985.
N.F. Curtis, Coord. Chem. Rev., 3, 3 (1968).
G.M. Shedri, Siemens SHELXTL-PC program package, Siemens Analytical X-Ray Instruments Inc., Madison, WI, 1990.
W.J. Geary, Coord. Chem. Rev., 7, 81 (1981).
L. Sacconi, J. Chem. Soc. (A), 248 (1970).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Shen, HY., Liao, DZ., Jiang, ZH. et al. Crystal structure and spectroscopic properties of a new five-coordinate mixed-ligand nickel(II) complex with a macrocyclic ligand: [Ni(trans[14]diene)SCN]ClO4 (trans[14]diene = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene). Transition Metal Chemistry 24, 581–583 (1999). https://doi.org/10.1023/A:1006995523043
Issue Date:
DOI: https://doi.org/10.1023/A:1006995523043