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Structure and magnetic properties of a new dinuclear nickel(II) complex with a dinucleating hexaazamacrocycle

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Abstract

The crystal structure and magnetic properties of a new dinuclear nickel(II) complex [LNi2(AcO)4]·14H2O, where L = 3,6,9,17,20,23-hexaazatricyclo [23.3.1.111,13] triaconta-1(29),11(30),12,14,25(26),27-hexene, has been studied. X-ray structure analysis shows that the compound consists of a discrete [LNi2(AcO)4] complex and 14 lattice water molecules. Each Ni atom is six coordinated by three N atoms from the macrocycle and three O atoms from the two coordinated acetates; two nickel atoms in each macrocycle are at the distance of 7.028Å. The result of the magnetic measurement indicates that the zero-field splitting constant of nickel(II) centres |D| = 1.87 cm−1.

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References

  1. J. L. Pierre, P. Chautemps, S. Refnif, C. Beguin, A. E. Marzouki, G. Serratrice, E. Saint-Aman and P. Rey, J. Am. Chem. Soc., 117, 1965 (1995).

    Google Scholar 

  2. D. A. Nation, J. H. Reibenspies and A. E. Martell, Inorg. Chem., 35, 4597 (1996).

    Google Scholar 

  3. M. G. B. Drew, C. J. Harding, O. W. Howarth, Q. Lu, D. J. Marrs, G. G. Morgan, V. McKcc and J. Nelson, J. Chem. Soc., Dalton Tans., 3021 (1996).

  4. M. Mikuriya, I. Murase, E. Asato and S. Kida, Chem. Lett., 497 (1989).

  5. C. A. Salata, M.-T. Youinou and C. J. Burrows, Inorg. Chem., 30, 3454 (1991).

    Google Scholar 

  6. R. Menif and A. E. Martell, J. Chem. Soc., Chem. Commun., 1522 (1989).

  7. N. L. Kirillova, Y. T. Struchkov, M. A. Porai-Koshits, T. C. Idrisov and V. T. Kalinnikov, Inorg. Chim. Acta, 40, 115 (1980).

    Google Scholar 

  8. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th Edit., Wiley: New York, 1986, p. 231.

    Google Scholar 

  9. B. Bleaney and K. D. Bowers, Proc. Roy. Soc. (London) Ser. A, 214, 451 (1952).

    Google Scholar 

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Authors and Affiliations

  1. State Key Laboratory of Coordination Chemistry, Institute of Coordination Chemistry, Nanjing University, Nanjing, 210093, P.R. China

    Hai-Liang Zhu, Mei-Fang Wu, Li-Min Zheng, Pei Huang & Wen-Xia Tang

  2. Key Laboratory of Superamolecular Structure and Spectroscopy of, Jilin University, Jilin, 130023, P.R. China

    Wei-Ming Bu

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  1. Hai-Liang Zhu
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  2. Mei-Fang Wu
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  3. Li-Min Zheng
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  4. Pei Huang
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  5. Wen-Xia Tang
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  6. Wei-Ming Bu
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Zhu, HL., Wu, MF., Zheng, LM. et al. Structure and magnetic properties of a new dinuclear nickel(II) complex with a dinucleating hexaazamacrocycle. Transition Metal Chemistry 24, 346–349 (1999). https://doi.org/10.1023/A:1006972423053

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  • DOI: https://doi.org/10.1023/A:1006972423053

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