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An Intercomparison of NO2 and OClO Measurements at Arrival Heights, Antarctica during Austral Spring 1996

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Abstract

For several years NO2 and OClO, two species important to understanding ozone destruction in the Antarctic stratosphere, have been measured at Arrival Heights, Antarctica by two groups: New Zealand's National Institute of Water and Atmospheric Research (NIWA) and the NOAA Aeronomy Laboratory in Boulder, Colorado. Using data independently collected by these two groups during the Austral spring of 1996, it is shown that the two data sets are in extremely close agreement. Besides offering validation of the instrumentation and analysis techniques of both groups, this result provides confidence in the more complete history of these species gained by combining the two data sets.

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References

  • Anderson, J. G., Brune, W. H., and Proffitt, M. H., 1989: Ozone destruction by chlorine radicals within the Antarctic vortex: The spatial and temporal evolution of ClO-O3 anticorrelation based on in situ ER-2 data, J. Geophys. Res. 94, 11465–11479.

    Google Scholar 

  • Box, G. E. P., Hunter, W. G., and Hunter, J. S., 1978: Statistics for Experimenters, John Wiley & Sons, New York.

    Google Scholar 

  • Brasseur, G. and Solomon, S., 1984: Aeronomy of the Middle Atmosphere, D. Reidel, Hingham, Massachusetts.

    Google Scholar 

  • Burkholder, J. D. and Talukdar, R. K., 1994: Temperature dependence of the ozone absorption spectrum over the wavelength range 410 to 760 nm, Geophys. Res. Lett. 21, 581–584.

    Google Scholar 

  • Coquart, B., Jenouvrier, A., and Merienne, M. F., 1995: The NO2 absorption spectrum, II, Absorption cross sections at low temperatures in the 400-500 nm region, J. Atmos. Chem. 21, 251.

    Google Scholar 

  • Crutzen, P. J., The influence of nitrogen oxide on the atmospheric ozone content, Q. J. R. Meterorol. Soc. 96, 320.

  • Davidson, J. A., Cantrell, C. A., McDaniel, A. H., Shetter, R. E., Madronich, S., and Calvert, J. G., 1988: Visible-ultraviolet absorption cross sections for NO2 as a function of temperature, J. Geophys. Res. 93, 7105.

    Google Scholar 

  • Harder, J. W., Brault, J. W., Johnston, P. V., and Mount, G. H., 1997: Temperature dependent NO2 cross sections at high spectral resolution, J. Geophys. Res. 102, 3861–3879.

    Google Scholar 

  • Harwood, M. H. and Jones, R. L., 1994: Temperature dependent ultraviolet-visible absorption cross sections of NO2 and N2O4: Low-temperature measurements of the equilibrium constant for 2NO2 = N2O4, J. Geophys. Res. 99, 22955.

    Google Scholar 

  • Hofmann, D., Bonasoni, P., De Maziere, M., Evangelisti, F., Giovanelli, G., Goldman, A., Goutail, F., Harder, J., Jakoubek, R., Johnston, P., Kerr, J., Matthews, W. A., McElroy, T., McKenzie, R., Mount, G., Platt, U., Pommereau, J.-P., Sarkissian, A., Simon, P., Solomon, S., Stutz, J., Thomas, A., Van Roozendael, M., and Wu, E., 1995: Intercomparison of UV/visible spectrometers for measurements of stratospheric NO2 for the Network for the Detection of Stratospheric Change, J. Geophys. Res. 100, 16765–16791.

    Google Scholar 

  • Johnston, H. S., 1971: Reduction of stratospheric ozone by nitrogen oxide catalysts from supersonic transport exhaust, Science 173, 517.

    Google Scholar 

  • Johnston, H. S. and Podolske, J., 1971: Interpretation of stratospheric photochemistry, Rev. Geophys. 16, 491.

    Google Scholar 

  • Keys, J. G. and Johnston, P. V., 1986: Stratospheric NO2 and O3 in Antarctica: Dynamic and chemically controlled variations, Geophys. Res. Lett. 13, 1260.

    Google Scholar 

  • Kreher, K., Keys, J. G., Johnston, P. V., Platt, U., and Liu, X., 1996: Ground-based measurements of OClO and HCl in austral spring 1993 at Arrival Heights, Antarctica, Geophys. Res. Lett. 23, 1545–1548.

    Google Scholar 

  • McElroy, M. B., Salawitch, R. J., Wofsy, S. C., and Logan, J. A., 1986: Antarctic ozone: Reductions due to synergistic interactions of chlorine and bromine, Nature 321, 759.

    Google Scholar 

  • McKenzie, R. L. and Johnston, P. V., 1984: Springtime stratospheric NO2 in Antarctica, Geophys. Res. Lett. 11, 73.

    Google Scholar 

  • Mount, G. H., Sanders, R. W., Schmeltekopf, A. L., and Solomon, S., 1987: Visible spectroscopy at McMurdo Station, Antarctica, 2, Overview and daily variations of NO2 and O3, austral spring, 1986, J. Geophys. Res. 92, 8320–8328.

    Google Scholar 

  • Perliski, L. M. and Solomon, S., 1993: On the evaluation of air mass factors for atmospheric nearultraviolet and visible absorption spectroscopy, J. Geophys. Res. 98, 10363–10374.

    Google Scholar 

  • Roscoe, H. K., Johnston, P. V., Van Roozendael, M., Richter, A., Roscoe, J., Preston, K. E., Lambert, J.-C., Hermans, C., DeCuyper, W., Dzienus, S., Winterrath, T., Burrows, J., Sarkissian, A., Goutail, F., Pommereau, J.-P., D'Almeida, E., Hottier, J., Coureul, C., Didier, R., Pundt, I., Barlett, L. M., McElroy, C. T., Kerr, J. E., Elokhov, A., Giovanelli, G., Ravengnani, F., Premuda, M., Kostadinov, I., Erle, F., Wagner, T., Pfielsticker, K., Kenntner, M., Marquard, L. C., Gil, M., Puentedura, O., Arlander, W., Kastad Hoiskar, B. A., Tellefsen, W., Heese, B., Jones, R. L., Aliwell, S. R., and Freshwater, R. A., Slant column measurements of O3 and NO2 during the NDSC intercomparison of zenith-sky UV-visible spectrometers in June 1996, J. Atmos. Chem. (accepted, October 1998).

  • Sanders, R. W., 1996: Improved analysis of atmospheric absorption spectra by including the temperature dependence of NO2, J. Geophys. Res. 101, 20945–20952.

    Google Scholar 

  • Schiller, C. and Wahner, A. 1996: Comment on 'stratospheric OClO measurements as a poor quantitative indicator of chlorine activation' by Sessler, J., Chipperfield, M. P., Pyle, J. A., and Toumi, P., Geophys. Res. Lett. 23, 1053–1054.

    Google Scholar 

  • Solomon, S., Garcia, R. R., Rowland, F. S., and Wuebbles, D. J., 1986: On the depletion of Antarctic ozone, Nature 321, 755.

    Google Scholar 

  • Solomon, S., Schmeltekopf, A. L., and Sanders, R. W., 1987: On the interpretation of zenith sky absorption measurements, J. Geophys. Res. 92, 8311–8319.

    Google Scholar 

  • Solomon, S., Mount, G. H., Sanders, R. W., Schmeltekopf, A. L., 1987a: Visible spectroscopy at McMurdo Station, Antarctica 2, Observations of OClO, J. Geophys. Res. 92, 8329–8338.

    Google Scholar 

  • Solomon, S., Sanders, R. W., Carroll, M. A., and Schmeltekopf, A. L., 1989: Visible and nearultraviolet spectroscopy at McMurdo Station, Antarctica 5. Observations of the diurnal variations of BrO and OClO, J. Geophys. Res. 94, 11393–11403.

    Google Scholar 

  • Stutz, J. and Platt, U., 1992: Problems in using diode arrays for open path DOAS measurements of atmospheric species, Proc. EOS/SPIE Symp. Berlin, Optical Methods in Atmospheric Chemistry 1715, 329–340.

    Google Scholar 

  • Wahner, A., Tyndall, G. S., and Ravishankara, A. R., 1987: Absorption cross sections for OClO as a function of temperature in the wavelength range 240-480 nm, J. Chem. Phys. 91, 2735–2738.

    Google Scholar 

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Sanders, R.W., Solomon, S., Kreher, K. et al. An Intercomparison of NO2 and OClO Measurements at Arrival Heights, Antarctica during Austral Spring 1996. Journal of Atmospheric Chemistry 33, 283–298 (1999). https://doi.org/10.1023/A:1006185027584

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  • DOI: https://doi.org/10.1023/A:1006185027584

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