Skip to main content
SpringerLink
Log in

Ternary Complexation of Manganese(II) and Cadmium(II) with 1,10-Phenanthroline and Halide or Thiocyanato Ions in N,N-Dimethylformamide

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Ternary complexation of manganese(II) and cadmium(II) with1,10-phenanthroline (phen), and halide (chloride, bromide) or pseudohalide (thiocyanate) ions asligands has been studied by precise titration calorimetry inN,N-dimethylformamide (DMF) at 25°C. Data obtained for the ternary system were analyzed onthe basis of thermodynamic parameters for the binary MII-phen and MII-X-(M= Mn or Cd, X = Cl, Br, or SCN) systems. In the binary MII-phen system,formation of a series of mono- to tris- 1,10-phenanthroline complexes isestablished and the formation constants and reaction enthalpies and entropies areobtained. Thermodynamic parameters of complexation for the MII-X- systemshave previously been obtained. All titration curves obtained in the ternary systemsare explained well in terms of formation of mononuclear complexes of the type[MX m (phen) N ](2−m)+. With manganese(II), formation of [MnX(phen)]+,[MnX2(phen)], [MnX3(phen)]−,[MnX(phen)2]+, and[MnX2(phen)] is establishedfor X = Cl and SCN, and [MnX(phen)]+, [MnX2(phen)], [MnX(phen)2]+, and[MnX2(phen)2] for X = Br. With cadmium(II), formation of [CdX(phen)]+,[CdX2(phen)], [CdX3(phen)]−, [CdX(phen)2]+, and [CdX2(phen)2], is establishedfor X = Cl and Br, and [CdX(phen)]+, [CdX2(phen)], [CdX(phen)2]+, and[CdX2(phen)2] for X = SCN. The formation constants, and reaction enthalpiesand entropies are obtained. The results are discussed in comparison with thosefor the corresponding 2,2′-bipyridine systems.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. G. A. Barclay, B. F. Hoskins, and C. H. L. Kennard, J Chem. Soc., p. 5691 (1963).

  2. C. W. Reimann, S. Block, and A. Perloff, Inorg. Chem. 5, 1185 (1966).

    Google Scholar 

  3. E. D. Mckenzie, Coord. Chem. Rev. 31, 783 (1971).

    Google Scholar 

  4. F. S. Stephens and P. A. Tucker, J. Chem. Soc. Dalton Trans., p. 2293 (1973).

  5. J. Keiser, G. Brauner, F. A. Schröder, I. F. Taylor, and S. E. Ramussen, J. Chem. Soc. Dalton Trans., p. 1490 (1974).

  6. W. D. Harrison, B. J. Hathaway, and D. Kennedy, Acta Crystallogr. B 35, 2301 (1979).

    Google Scholar 

  7. B. J. Hathaway and A. Murphy, Acta Crystallogr. B 36, 295 (1980).

    Google Scholar 

  8. M. N. Hughes, Coord. Chem. Rev. 37, 297 (1981).

    Google Scholar 

  9. A. Walsh, B. Walsh, B. Murrphy, and B. J. Hathaway, Acta Crystallogr. B 37, 1512 (1981).

    Google Scholar 

  10. M. A. Kahn and D. G. Tuck, Acta Crystallogr. B 37, 1409 (1981).

    Google Scholar 

  11. M. A. Kahn and D. G. Tuck, Acta Crystallogr. C 40, 60 (1984).

    Google Scholar 

  12. E. C. Constable, Coord. Chem. Rev. 58, 1 (1984).

    Google Scholar 

  13. H. Irving and D. H. Miller, J. Chem. Soc., p. 3457 (1955).

  14. G. Atkinson and J. Bauman, Inorg. Chem. 1, 900 (1962).

    Google Scholar 

  15. H. Irving and D. Mellor, J. Chem. Soc. 5222, 5237 (1962).

    Google Scholar 

  16. G. Anderegg, Helv. Chim. Acta 46, 1833, 2813 (1963).

    Google Scholar 

  17. G. Anderegg, Helv. Chim. Acta 46, 2397 (1963).

    Google Scholar 

  18. R. L. Davies and K. W. Dunning, J. Chem. Soc., p. 4168 (1965).

  19. D. D. Perrin and V. S. Sharma, J. Inorg. Nuclear Chem. 28, 1271 (1966).

    Google Scholar 

  20. C. Luca, Bull. Soc. Chim. Fr., p. 2556 (1967).

  21. D. Hague and S. Martin, J. Chem. Soc. Dalton Trans., p. 254 (1974).

  22. H. Sigel, B. Fisher, and B. Prijs, J. Am. Chem. Soc. 99, 4489 (1977).

    Google Scholar 

  23. W. A. E. McBryde, A Critical Review of Equilibrium Data for Proton-and Metal Complexes of 1,10-Phenanthroline and 2,2′-Bipyridyl and Related Compounds, IUPAC Chemical Data Series No 17, (Pergamon Press, Oxford, 1978).

    Google Scholar 

  24. Y. Abe and G. Wada, Bull. Chem. Soc. Jpn. 54, 3334 (1981).

    Google Scholar 

  25. M. Emara and M. Bahr, Bull. Soc. Chim. Fr., p. 25 (1983).

  26. Y. Abe and G. Wada, Bull. Chem. Soc. Jpn. 60, 1936 (1987).

    Google Scholar 

  27. M. Ignaczak and G. Andrijewski, Zhur. Neorg. Khim. 35, 1710 (1990).

    Google Scholar 

  28. S. Ishiguro, L. Nagy, and H. Ohtaki, Bull. Chem. Soc. Jpn. 60, 2053 (1987).

    Google Scholar 

  29. S. Ishiguro, L. Nagy, and H. Ohtaki, Bull. Chem. Soc. Jpn. 60, 2865 (1987).

    Google Scholar 

  30. S. Ishiguro, K. Ozutumi, L. Nagy, and H. Ohtaki, J. Chem. Soc. Dalton Trans., p. 655 (1989).

  31. S. Ishiguro and K. Ozutumi, Bull. Chem. Soc. Jpn. 62, 2392 (1989).

    Google Scholar 

  32. S. Ishiguro, K. Ozutumi, M. Miyauchi, and H. Ohtaki, Inorg. Chem. 28, 3258 (1989).

    Google Scholar 

  33. S. Ishiguro, K. Ozutumi, and A. Ohtaki, Bull. Chem. Soc. Jpn. 63, 3030 (1990).

    Google Scholar 

  34. S. Ishiguro, M. Miyauchi, and K. Ozutumi, J. Chem. Soc. Dalton Trans., p. 2035 (1990).

  35. M. Komiya, S. Yoshida, and S. Ishiguro, J. Solution Chem. 26, 997 (1997).

    Google Scholar 

  36. H. Suzuki and S. Ishiguro, Netsu Sokutei 15, 152 (1988).

    Google Scholar 

  37. S. Ishiguro, T. Takamuku, and H. Ohtaki, Bull. Chem. Soc. Jpn. 61, 3901 (1988).

    Google Scholar 

  38. S. Ishiguro, K. Ozutumi, and H. Ohtaki, J. Chem. Soc. Faraday Trans. 84, 2409 (1988).

    Google Scholar 

  39. K. Ozutumi and S. Ishiguro, J. Chem. Soc. Faraday Trans. 86, 271 (1990).

    Google Scholar 

  40. S. Ishiguro and K. Ozutumi, Inorg. Chem. 29, 1117 (1990).

    Google Scholar 

  41. M. Komiya, T. Tamada, and S. Ishiguro, unpublished data.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Higashi-ku, Fukuoka, 812-8581, Japan

    Morito Komiya & Shin-ichi Ishiguro

  2. Department of Electronic Chemistry, Tokyo Institute of Technology at Nagatsuta, Midori-ku, Yokohama, 226-8502, Japan

    Satoshi Yoshida

Authors
  1. Morito Komiya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Satoshi Yoshida
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Shin-ichi Ishiguro
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Komiya, M., Yoshida, S. & Ishiguro, Si. Ternary Complexation of Manganese(II) and Cadmium(II) with 1,10-Phenanthroline and Halide or Thiocyanato Ions in N,N-Dimethylformamide. Journal of Solution Chemistry 29, 101–129 (2000). https://doi.org/10.1023/A:1005173215167

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1005173215167

Search

Navigation