Abstract
Spheroidal carbonaceous particles (SCP) and trace metals (Cd, Cu, Pb, Ni, V and Zn) were analysed from 75 lake surface sediments across the UK. Trace metals were additionally analysed from catchment mosses (Hylocomium splendens and Pleurozium schreberi) from 43 of the sites but were absent from the remainder. Spatial distribution of SCP concentration and trace metal concentrations in sediments and mosses showed good agreement with each other and with known emission sources. Particles were allocated to their fuel-type and spatial trends in these data showed good agreement with potential sources. High areas of oil particle deposition were identified in the south-east of England, Merseyside, Galloway / Northern Ireland, the Firth of Forth and eastern Scotland. Oil SCP concentrations showed good agreement with Ni and V concentrations in mosses suggesting an atmospheric source for these metals from the combustion of this fuel. Characterised SCP trends also showed good agreement with predictions from models such as HARM and EMEP. Most high deposition areas of metals and particles were found to coincide with population centres suggesting a possible impact on human health.
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Bacci, P., Del Monte, M., Longhetto, A., Piano, A., Prodi, F., Redaelli, P., Sabbioni, C. and Ventura, A.: 1983, J. Aerosol Sci. 14, 557-572.
Barell, K., Seland, O., Foss, A., Mylona, S., Sandnes, H., Styve, H. and Tarrason, L.: 1995, European transboundary acidifying air pollution. Ten years calculated fields and budgets to the end of the first sulphur protocol. EMEP/MSC-W Report 1/95.
Battarbee, R.W., Anderson, N.J., Appleby, P.G., Flower, R.J., Fritz, S.C., Haworth, E,Y., Higgitt, S., Jones, V.J., Kreiser, A., Munro, M.A.R., Natkanski, J., Oldfield, F., Patrick, S.T., Richardson, N.G., Rippey, B. and Stevenson, A. C.: 1988, Lake Acidification in the United Kingdom 1800-1986. ENSIS Publishing. London, 68pp.
Bull, K.R.:1991, Env. Pollut. 69, 105-123.
Critical Loads Advisory Group (CLAG): 1994. Critical loads of acid deposition for United Kingdom freshwaters. Department of the Environment.
Committee on the Medical Effects of Air Pollutants (COMEAP) (1995) Non-biological particles and health. HMSO. London. 141 pp.
Davies, T.D., Abrahams, P.W., Tranter, M., Blackwood, I., Brimblecombe, P. and Vincent C.E,: 1984, Nature. 312, 58-61.
Dockery, D.W., Pope, C.A., Xu, X., Spengler, J.D., Ware, J.H., Fay, M.E., Ferris, B.G. and Speizer, F.E.: 1993, New England J. Med. 329, 1753-1759.
Electricity Association.: 1997, Electricity Industry Review. 68pp. London.
Ganor, E., Altshuller, D., Foner, H.A., Brenner, S., and Gabbay, J.: 1988, Wat. Air Soil Poll. 42, 241-252.
Glew, J.R.: 1991, J. Paleolim. 5, 285-287.
Hill, M.O., Proston, C.D. and Smirh, A.J.E. (eds.): 1994, Atlas ofBryophytes of Britain and Ireland. Valume 3. Mosses. Harley Books.
King, A.M. and Dorling, S.: 1997. Atmos. Environ. 31, 2379-2383.
London Air Quality Network.: 1994. Air Quality in London. The Second Report of the LAQN.. South East Institute for Public Health.
Mamane, Y., Miller, J.L. and Dzubay, T.G.: 1986. Atmos. Environ. 20, 2125-2135.
Metcalfe, S.E. and Whyatt, J.D.: 1995. In: Battarbee, R.W. (ed.) Acid Rain and its Impact: The Critical Loands Debate p27-36. ENSIS Publishing. London.
Pacyna, M.:1984, Annos. Env. 18, 41-50.
Pope II, C.A., Dockery, D.W., Spengler, J.D. and Raizenne, M.E.: 1991, Am. Rev. Respir. Dis. 144, 668-674.
Rose, N.L.: 1994. J. Paleolim. 11, 210-204.
Rose N.L.: 1995, Sci. Tot. Env. 160/161, 487-496.
Rose, N.L. and Juggins, S.: 1994, Atmos, Env. 28, 177-183.
Rose, N.L. and Long, X.: 1996, J. Aerosol Sci. 27,Suppl. 1, S679-S680.
Rose, N.L., Juggins, S. and Watt, J.: 1996, Phil. Trans. Roy. Soc. Lond. (Series A). 452, 881-907.
Rose, N.L., Alliksaar, T., Bowman, J.J., Boyle, J.F, Coles, B., Fott, J., Harlock, S., Juggins, S., Punning, J-M., St. Clair-Gribble, K., Vukic, J. and Watt, J.: this volume, Wat. Air Soil Poll.
Rühling, A.; 1994, Atmospheric heavy metal deposition in Europe-estimation based on moss analysis. Nord 1994:9.
Steinnes, E., Rambaek, J.P. and Hanssen, J.E.: 1992, Chemosphere. 25, 735-752.
Steinnes, E., Hanssen, J.E., Rambaek, J.P. and Vogt, N.B.: 1994, Water, Soil Pollut. 74, 121-140.
Swift, D.L.; 1995, lnhalation Toxicol. 7, 125-130.
Thompson, M. and Wood, S.: 1982, Atomic absorption spectrometry. Elsevier. p261-284.
Wallen, C.C. (ed.): 1970, Climates of northern and western Europe. World Survey of Climatology Volume 5. Elsevier Publishing, Amsterdam. 253pp.
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Rose, N., Harlock, S. The Spatial Distribution of Characterised Fly-Ash Particles and Trace Metals in Lake Sediments and Catchment Mosses in the United Kingdom. Water, Air, & Soil Pollution 106, 287–308 (1998). https://doi.org/10.1023/A:1005041328939
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DOI: https://doi.org/10.1023/A:1005041328939