Abstract
As a part of the FLAME research project funded by the EU COPERNICUS programme (1994-1996) samples of surface sediments were taken from 31 man-made lakes and one natural lake in the Czech Republic. The sites differ considerably in their altitude, area, catchment, depth, retention time, trophic status, and in parameters of local air pollution. The samples were analysed for concentration of spheroidal carbonaceous particles (SCP, numbers per gram dry mass of sediment), a characteristic component of industrial fly-ash. The extracted carbonaceous particles were allocated according to the fuel-types combusted throughout Europe (coal, oil, brown coal, peat, oil shale) using particle chemistries derived by energy dispersive spectroscopy (EDS). Trace metals were also analysed in the surface sediments as were mosses sampled at the study sites. The main objectives of the study were (i) to look for factors determining SCP concentrations in surface sediments of lakes, with special emphasis on the distribution of large fossil-fuel combustion sources (ii) to compare fuel-type allocation of carbonaceous particles with combustion of these fuels within the country, (iii) to look for trends in spatial distribution of trace metals and (iv) to characterize the impact of airborne particles from these sources on environmental and human health. The SCP concentrations show little or no relation to air-pollution parameters on a small scale, although some large-scale effects are evident. A good relationship was, however, found to site characteristics such as altitude and lake area : catchment area. The reason, why this relationship is more apparent from our dataset than from any other study published so far, is likely to be based on the high variation in the physical parameters (altitude, lake and catchment area) of the sites under study. The distribution of particles attributed to brown coal combustion are in good agreement with the distribution of major air pollution sources across the country but the fraction of particles attributed to coal seems to be overestimated by the present technique. The distribution of trace metals in surface sediments are also in agreement with expected sources. The usefulness of SCP concentrations as indicators of stress to human and environmental health is briefly discussed.
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Alliksaar, T., and Punning, J-M.: this volume, Water, Air, and Soil Pollut.
Barrett, K., Seland, O., Foss, A., Mylona, S., Sandnes, H., Styve, H., and Tarrason, L.: 1995, European transboundary acidifying air polution. Ten years calculated fields and budgets to the end of the first sulphur protocol, EMEP/MSC-W Report 1/95.
Broman, D., Näf, C., Wik, M., and Renberg, I.: 1990. Chemosphere 21, 69-77.
Bowman, J.J. and Harlock, S.: this volume, Water, Air, and Soil Pollut.
Cerny, J. and Paces, T. (eds.): 1995, Acidification in the Black Triangle Region, Acid Reign '95, 5th International Conference on Acidic Deposition, Goteborg, Sweden, 26-30 June 1995, p. 96.
Czech Ecological Institute: 1995. (Environmental Yearbook of the Czech Republic), CEU. Prague, p. 304, (In Czech.)
Del Mont, M., Sabbioni, C., and Vittori, O.: 1984, Sci. Tot. Env. 36, 369-376.
Expert Panel on Air Quality Standards (EPAQS).: 1995, Particles. HMSO, London.
Fiala, J., Sladecek, J., Hunova, J., Ostatnieka. J., and Dvorakova, M. (eds.): 1995, Air Pollution in the Czech Republic, A Graphical Yearbook. Czech Hydrometeorological Institute, Praha, p. 178.
Fott, J., Prazakova, M., Stuchlik, E., and Stuchlikova, Z.: 1994, Hydrobiologia, 274, 37-47.
Kubeeka, J. and Hanslik, E.: 1996, in Hanslik, E, (ed.), Radionuklidy a ionizujici zareni ve vodnim hospodarstvi, CVVS, C. Budejovice. (in Czech.)
Kopaeek, J., Stuchlik, E., Fott, J., Vesely, J., and Hejzlar, J.: in press, Limnology and Oceanography.
Moldan, B. (ed.): 1990, (Environment in the Czech Republic. The development until the end of 1989), Academia, Praha, p. 281. (In Czech.)
Pope III, C.A., Duckery, D.W., Spengler, J.D., and Raizenne, M. E.; 1991, Am. Rev. Respir. Dis. 144, 668-674.
Pope III, C.A., Schwartz, J., and Ransom, M. R.: 1992, Arch. Env. Health, 47, 211-217.
Pyatt, F.B. and Haywood, W.J.: 1989, The Environmentalist 9, 291-298.
Rose, N.L. and Juggins, S.: 1994, Atmos. Env. 28, 177-183.
Rose, N.L., and Long, X.: 1996, J. Aerosol. Sci. 27,Suppl. 1, S679-S680.
Rose, N.L., and Harlock, S.: this volume, Water, Air, and Soil Pollut.
Rose, N.L., Alliksaar, T., Bowman, J.J., Boyle, J.F., Coles, B., Fott, J., Harlock, S., Juggins, S., Punning, J-M., St. Clair-Gribble, K., Vukic, J., and Watt, J.: this volume, Water, Air, and Soil Pollut.
Ross, H.R.: 1990, Water, Air, and Soil Pollut. 50, 63-76.
Rühling, A. (ed.): 1994, Nord 9, p. 53.
Schmidt, R., Arzet, K., Facher, E., Fott, J., Irlweck, K., Rehakova, Z., Rose, N., Straskrabova, V., and Vesely, J.: 1993, Acidification of Bohemian Lakes, Final Report, Ost-West Programm, Mondsee, p. 85.
TERPLAN: 1990, Czech Republic-protected and endangered areas, Map 1: 500 000, Praha.
Vleek, V. (ed.): 1984, (Rivers and Reservoirs), Zempisny lexikon CSR, Academia, Praha, p. 315. (In Czech.)
Walters, S., Griffiths, R.K., and Ayres, J.G.: 1994. Thorax 49, 133-140.
Wik, M., and Renberg, I.: 1991, Ambio 7, 289-292.
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Fott, J., Vukic, J. & Rose, N. The Spatial Distribution of Characterized Fly-Ash Particles and Trace Metals in Lake Sediments and Catchment Mosses: Czech Republic. Water, Air, & Soil Pollution 106, 241–261 (1998). https://doi.org/10.1023/A:1005037228031
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DOI: https://doi.org/10.1023/A:1005037228031