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Surface oxidation to improve water-based gelcasting of silicon nitride

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Abstract

During the process of water-based gelcasting of Si3N4, the gasdischarged due to the reactions on the solid-liquid interface canlead to a great deal of big bubbles in the green bodies. To improvethe process a type of method based on surface oxidation is developed.By means of the method a layer of SiO2 and Si2N2O, which can prohibitthe gas from being discharged effectively, is formed on the surfaceof Si3N4 powders. Oxidized powders can be dispersed better than those not oxidized, and after gas-pressure-sintering mechanical property of the gelcast samples made from the oxidized powder is much better thanthat of dry-pressed and then isostatic pressed samples.

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References

  1. J. L. Yang, Dissertation, Tsinghua University, Beijing, 1996.

  2. O. O. Omatete, M. A. Janney and R. A. Sterklow, Ceram. Bull. 70 (1991) 1641.

    Google Scholar 

  3. A. C. Young, O. O. Omatete, M. A. Janney and R. A. Strehlow, J. Am. Ceram. Soc. 74 (1991) 612.

    Google Scholar 

  4. M. A. Janney, W. J. Ren, G. H. Kirby, S. D. Nunn and S. Viswanathan, Materials and manufacturing processes 13 (1998) 389.

    Google Scholar 

  5. T. J. Graule, F. H. Baader and L. J. Bauckler, in Proceedings of 5th International Symposium on Ceram. Mater. and Comp. for Engines World Scientific, 1995, edited by D. S. Yan, X. R. Fu and S. X. Shi, p. 626.

  6. S. D. Nunn and G. H. Kirby, Ceram. Eng. Sci. Proc. 17 (1996) 209.

    Google Scholar 

  7. L. Sun, L. Gao, J. K. Guo and D. S. Yan, Acta Materials 9 (1996) 489.

    Google Scholar 

  8. B. Waesche and G. Steinborn, Key. Eng. Mater. 132-136(Pt 1) (1997) 374.

    Google Scholar 

  9. C. Bossel, J. Dutta, R. Houiet, J. Hilgorn and H. Hofmann, Mater. Sci. and Eng. A204 (1995) 107.

    Google Scholar 

  10. Q. Tang, Master Thesis, Tsinghua University, Beijing, 1998.

  11. Qiang Tang, Zhipeng Xie, Jinglong Yang and Yong Huang, J. Mater. Sci. 17 (1998) 1239.

    Google Scholar 

  12. S. Mezzasalma and D. Baldovino, J. Coll. and Inter. Sci. 180 (1996) 413.

    Google Scholar 

  13. P. Greil, R. Nitzsche, H. Friedrichand W. Hermel, J. Eur. Ceram. Soc. 7 (1991) 353.

    Google Scholar 

  14. R. T. Sanchez, A. B. Garcia and A. M. Cesio, ibid. 16 (1996) 1127.

    Google Scholar 

  15. A. Nagel, G. Petzow and P. Greil, ibid. 5 (1989) 371.

    Google Scholar 

  16. C. Hu and M. N. Rahaman, J. Am. Ceram. Soc. 76 (1993) 2549.

    Google Scholar 

  17. Z. P. Xie, Y. Huang and J. G. Wu, J. Mater. Sci. Lett. 14 (1995) 1165.

    Google Scholar 

  18. M. Castanho, J. L. G. Fierro and R. Moreno, J. Euro. Ceram. Soc. 17 (1997) 383.

    Google Scholar 

  19. M. Castanho, R. Moreno and J. L. G. Fierro, J. Mater. Sci. 32 (1997) 157.

    Google Scholar 

  20. K. Brow and C. G. Pantano,J. Am. Ceram. Soc. 69 (1986) 314.

    Google Scholar 

  21. A. Kitahara and A. Watanabe, in “Electric Phenomena of Interface” (Peking University Press, Beijing, 1992) p. 49.

    Google Scholar 

  22. J. Q. Dai, Z. P. Xie, Y. Huang, L. G. Ma and L. J. Zhou, J. Mater. Sci. Lett. 18 (1999) 1739.

    Google Scholar 

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Huang, Y., Ma, L., Tang, Q. et al. Surface oxidation to improve water-based gelcasting of silicon nitride. Journal of Materials Science 35, 3519–3524 (2000). https://doi.org/10.1023/A:1004897026241

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