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Production of CuInSe2 thin films by a sequential processes of evaporations and selenization

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Abstract

Thin films of copper indium diselenide (CuInSe2) were prepared by selenization of CuInSe2-Cu-In multilayered structure on glass substrate. The selenization procedure was carried out in a vapour of elemental selenium in a vacuum chamber. The obtained films were characterised by XRD and SEM measurements. The effects of substrate temperature on the structural, electrical and optical properties were studied. It was found that single phase CuInSe2 thin films with significant adhesion to substrate can be produced by selenization of CuInSe2-Cu-In multilayered structure at 450°C, when the first non single phase CuInSe2 layer was deposited at substrate temperature of 400°C. The thin films were found to be direct band gap semiconductors with a band gap of 0.97 eV.

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References

  1. R. A. Mickelsen, W. S. Chen, B. J. Stanbery, H. Bursch, J. M. Stewart, Y. R. Hsiao and W. Devaney, in Proceedings of the 18th IEEE Photovoltaic Specialist Conference (1985) p. 1069.

  2. L. Stolt, H. J. Hedstrom, J. Kessler, M. Ruckh, K. O. Velthaus and H. W. Schock, Appl. Phys. Lett. 62 (1993) 597.

    Google Scholar 

  3. H. Neumann, G. KÜhn and B. Schumann, Prog. Crystal Growth Char. 3 (1981) 157.

    Google Scholar 

  4. A. Ashida, Y. Hachiuma, N. Yamamoto, T. Ito and Y. Cho, J. Mater. Sci. Lett. 13 (1994) 1181.

    Google Scholar 

  5. C. Guillen and J. Hesrevo, J. Appl. Phys. 71 (1992) 5479.

    Google Scholar 

  6. B. BaŞol, Turkish J. Physics 17(4) (1993) 221.

    Google Scholar 

  7. S. P. Grindle, A. H. Clark, S. Rezaie-Serej, E. Falconer, J. McNeily and L. L. Kazmersky, J. Appl. Phys. 51 (1980) 5464.

    Google Scholar 

  8. V. Alberts and R. Swanepoel, Journal of Material Sciences: Materials in Electronics 7 (1996) 91.

    Google Scholar 

  9. J. Szot and U. Prinz, J. Appl. Phys. 66(12) (1989) 6077.

    Google Scholar 

  10. S. Zweigart, D. Schmid, J. Kessler, H. Dittrich and H. W. Schock, J. Crystal Growth 146 (1995) 233.

    Google Scholar 

  11. D. K. Schroder, “Semiconductor Material and Device Characterization” (New York, 1990).

  12. W. HÖrig, H. Neumann, H. J. HÖbler and G. KÜhn, Phys. Stat. Sol. (b) 80 (1977) K21.

    Google Scholar 

  13. J. Kessler, H. Dittrich, F. Grunwald and H. W. Schock, in Proceedings of the 10th European Photovoltaic Solar Energy Conference (1991) p. 879.

  14. B. Dimmler, A. Content and H. W. Schock, in Proceedings of the 10th European Photovoltaic Solar Energy Conference (1991) p. 875.

  15. R. Noufi, R. Axton, C. Herrington and S. K. Deb, Appl. Phys. Lett. 45(6) (1984) 668.

    Google Scholar 

  16. J. R. Tuttle, M. Contreras, M. H. Bode, D. Niles, D. S. Albin, R. Matson, A. M. Gabor, A. Tennant, A. Duda and R. Noufi, J. Appl. Phys. 77(1) (1995) 153.

    Google Scholar 

  17. L. L. Kazmersky, M. Hallerdt and P. J. Ireland, J. Vac. Sci. Technol. A(2) (1983) 395.

    Google Scholar 

  18. B. A. Mansour and M. A. El-Hagary, Phys. Stat. Sol. (a) 46 (1994) 669.

    Google Scholar 

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Sadigov, M.S., Özkan, M., Bacaksiz, E. et al. Production of CuInSe2 thin films by a sequential processes of evaporations and selenization. Journal of Materials Science 34, 4579–4584 (1999). https://doi.org/10.1023/A:1004670112975

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  • DOI: https://doi.org/10.1023/A:1004670112975

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