Abstract
Nanocomposite coatings have been deposited on plastic substrates by the dipping–drawing technique. The coatings were constituted by a matrice of a hybrid organomineral gel and a reinforcement made of amorphous silica. Two methods by which increase the silica content were investigated: silica was added via a silicon alkoxide compound or via dense silica particles of 10 nm size. Young's modulus and the hardness of the coating were measured using home-built equipment, and results compared to literature models. It is shown that the agreement between models and experimental values depends on the method of preparation of the nanocomposite coating. On the other hand, deviations appear when the volume fraction of reinforcement surpasses the three-dimensional percolation threshold.
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References
B. J. Briscoe and D. Tabor, Br Polym. J. 10 (1978) 54.
H. Dislich and E. Hussman, Thin Solid Films 77 (1981) 129.
C. J. Brinker and G. W. Scherer, “Sol-Gel Science”” (Academic Press, New York, NY 1990).
D. C. Bradley, R. C. Mehrotra and D. P. Gaur, “Metal alkoxides”” (Academic Press, New York, NY 1978).
H. Schmidt, J. Non-Cryst. Solids 73 (1985) 681.
P. Etienne, J. Denape, J. Y. Paris, J. Phalippou and R. Sempere, J. Sol-Gel Sci. Technol. 6 (1996) 287.
M. Buijs, J. Am. Ceram. Soc. 77 (1994) 1676.
T. Hanada, Y. Bessyo and N. Soga, J. Non-Cryst. Solids 113 (1989) 213.
A. Haddalena and A. Raccanelli, ibid. 151 (1992) 115.
D. Schweider, T. Schwarz and B. Schultrich, Thin Solid Films 219 (1992) 92.
P. Etienne, R. Sempere and J. Phalippou, J. Sol-Gel Sci. Technol. 2 (1994) 171.
J. L. Loubet, J. M. Georges, O. Marchesini and G. Meille, J. Tribol. 106 (1984) 43.
D. Fabes and W. C. Oliver, J. Non-cryst. Solids 121 (1990) 348.
E. S. Berkovich, Ind. Diamond Rev. 11 (1951) 129.
M. F. Doerner and W. D. Nix, J. Mater. Res. 1 (1986) 601.
S. Timoshenko, “Strength of materials”, Parts 1 and 2 (Van Nostrand, New York, NY 1935).
B. Scherrer, “Biostatistique” (Gaëtan Morin, Quebec 1984).
W. Voigt, in “Lehrbuch der Kristallophysik” (ed. Teubner, Berlin 1910).
W. Reuss, Z. Angew. Math. Mech. 9 (1929) 49.
Z. Hashin and S. Shtrikman, J. Mech. Phys. 11 (1963) 127.
O. Ishai and L. J. Cohen, Int. J. Mech. Sci. 9 (1967) 539.
J. C. Smith, Polym. Eng. Sci. 16 (1976) 394.
T. G. Richard, J. Mater. Sci 9 (1975) 108.
D. Stauffer, Phys. Rev. 54 (1979) 1.
M. I. Gai, L. I. Manevich and V. G. Oshmian, Sov. Phys. Dokl. 29 (1984) 505.
R. W. Rice, J. Mater. Sci. 14 (1979) 2768.
“SUPRASIL, Optical transparent fused silica”, (Heraeus S.A, Z. A. Countaboenf-BP18 F-91941 Les ULIS Cedex, France), Edition 1994.
N. Miyata and H. Jinno, J. Mater. Sci. 17 (1982) 547.
D. M. March, Proc.R. Soc.Lond. A279 (1964) 410.
D. Tabor, Rev. Phys. Tech. 1 (1970) 145.
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Etienne, P., Phalippou, J. & Sempere, R. Mechanical properties of nanocomposite organosilicate films. Journal of Materials Science 33, 3999–4005 (1998). https://doi.org/10.1023/A:1004609115560
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DOI: https://doi.org/10.1023/A:1004609115560