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Design of Selective Catalysts for Oxidative Dehydrogenation

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Abstract

Iron phosphate catalysts possess a unique selectivity to oxidative dehydrogenation. Unlike catalysts consisting of molybdenum and/or vanadium, they have no double-bond oxygen species (M=O), which are considered to be responsible for the oxygen insertion function and, as a result, for the degradation by C–C bond fission. The defect of iron phosphate catalysts is their lack of oxidation activity. The addition of a very small amount of molybdenum to iron phosphate markedly enhances the oxidation activity without modifying the high selectivity that originates from iron phosphate.

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  1. Niigata Institute of Technology, 1719, Fujihashi, Kashiwazaki 1195, Japan

    M. Ai

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  1. M. Ai
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Ai, M. Design of Selective Catalysts for Oxidative Dehydrogenation. Kinetics and Catalysis 44, 198–201 (2003). https://doi.org/10.1023/A:1023348311213

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